{"text_format":"3","workbook":"xlsx","n_sheets":10,"sheets":["CurTiPot","   pH_calc   ","Titration","Simulation","Distribution","Fosforzuurbepaling","Fosforzuurbepaling (2)","Regression","Graphs","Database"],"not_rendered":{"charts":22,"images":6,"macros":1,"defined_names":40,"comments":10},"read":"whole","date_system":"1900"}

{"sheet":"CurTiPot","index":0,"n_rows":50,"n_cols":39,"rows_kept":50,"hidden":true}
[{"$nulls":17},"CurTiPot main features and uses"]
[{"$nulls":17},"•  pH calculation of aqueous solutions with activity coefficient and buffer capacity estimation (mixtures of up to seven hexaprotic systems)"]
[{"$nulls":17},"•  Virtual Titration with indicator color transition simulation, manual titrant addition with a digital burette, species distribution and pH vs. volume plot"]
[{"$nulls":17},"•  Simulation of simple and complex acid-base titration curves"]
[{"$nulls":17},"    »  automatic generation of curves with data equally spaced in pH or volume, in concentration (\"pH\") or activity (pH)"]
[{"$nulls":17},"    »  simulation of experimental random errors in pH and volume; overlay of multiple curves for comparison"]
[{"$nulls":17},"•  Data analysis of real and simulated curves"]
[{"$nulls":17},"    »  Evaluation of curves with enhanced accuracy by interpolation, spline smoothing and automatic endpoint detection"]
[{"$nulls":17},"    »  Non-linear data Regression for the determination of concentrations and refinement of pKa values"]
[{"$nulls":17},"•  Distribution diagrams of species, protonation of bases, isoelectric point and buffer capacity vs. pH and vs. volume of a titration"]
[{"$nulls":17},"•  Database with equilibrium constants (pKa) of 250 acid-base systems including amino acids and some indicators (expandable by the user) "]
[]
[{"$nulls":17},"No installation is needed. Download the latest release of CurTiPot from www.iq.usp.br/gutz/Curtipot_.html and open the file with Microsoft Excel® "]
[{"$nulls":17},"Read the License - hover the mouse over the cell with the red dot on the left (Q14)"]
[{"$nulls":17},"If you agree with all terms of the License, enable macros and use CurTiPot freely for non-commercial purposes"]
[{"$nulls":17},"To enable the execution of macro-instructions in MS Excel follow instructions at the right   ------->               ------->               ------->               ------->               ------->               ------->              ",{"$nulls":20},"How to enable the macro-instructions in Excel 2013, 2010 and 2007"]
[{"$nulls":17},"The Solver supplement is required only by the Regression module. Follow activation instructions given in the cell I19 of the module",{"$nulls":20},"     Needless to say, CurTiPot, freely distributed by the author since 1992,"]
[{"$nulls":38},"     is trustworthy and contains no harmful code."]
[{"$nulls":17},"The author reserves the right not to be responsible for the correctness, completeness, accuracy and bug-free operation of the freeware CurTiPot, provided \"as is\" without warranty of any kind",{"$nulls":20},"     All macros are fully removed when closing the file."]
[{"$nulls":17},"Activity coefficient calculations, available in the pH_calc, Simulation and Regression modules, are subject to the limitations of the Daniel equation at ionic strength >0.1 mol/L"]
[{"$nulls":17},"Due to the wide range of screen resolutions in use nowadays, some resizing/replacement of figures and objects may be required",{"$nulls":20},"1. Open a new blank Excel spreadsheet "]
[{"$nulls":17},"Please report errors and incompatibilities of CurTiPot for MS Excel  (PC and Mac)  to the author;",{"$nulls":10},"Use the e-mail: ","gutz@iq.usp.br",{"$nulls":8},"2. Click on the File tab (or the Office button, in Windows XP)(top left corner)"]
[{"$nulls":38},"3. Click on \"Options\" (bottom left)"]
[{"$nulls":38},"4. Click on \"Trust Center\" (bottom left)"]
[{"$nulls":17},"Enable macros (see cell R16 above); click on a tab at the bottom left of this page or press Ctrl + PgDn switch modules; follow instructions in the yellow balloons",{"$nulls":20},"5. Click on \"Trust Center Settings\" (bottom right)"]
[{"$nulls":17},"Titration could be a nice start for beginners; pH_calc has too much stuff to grasp at once, but the pH is highlighted in the dark blue cell H23",{"$nulls":20},"6. Click on \"Macro Settings\""]
[{"$nulls":17},"Read local instructions in comment boxes by placing the mouse on cells with red marks (like in Q14 and Q34 at this page);",{"$nulls":20},"7. Click on \"Disable macros with notification\""]
[{"$nulls":17},"Switch to the Simulation module and repeat the preloaded titration of phosphoric acid; start clicking on the buttons at the left of the figure; change some concentrations afterwards;",{"$nulls":20},"8. Click OK; follow steps 1 to 8 only once on each computer"]
[{"$nulls":17},"Find endpoints of your real or simulated curves with Evaluation. There are buttons to load the last titration curve from Simulation;",{"$nulls":20},"9. Open the CurTiPot file"]
[{"$nulls":17},"Play and learn with the Distribution module; enjoy the Graphs before you advance to the less simple but more powerful Regression module to fit concentrations and pKas;",{"$nulls":20},"10. When the \"Security warning\" shows up, click on it to enable content"]
[" "," "," "," "," "," "," "," "," "," "," "," "," "," "," "," ",null,"Save your data, settings and results in Curtipot_anyname.xls files to preserve the original software (optionally deleting unused spreadsheets, with exception of this first one);"]
[" "," "," "," "," "," "," "," "," "," "," ",{"$nulls":27},"How to enable macros in MS Excel 97-2003: "]
[" ",{"$nulls":16},"The software CurTiPot, version 1.0 for DOS (Borland Turbo Basic and Microsoft Disk Operating System), was created in 1991 and launched in 1992.",{"$nulls":20},"1. Open a new blank Excel spreadsheet "]
[" "," ",null,"Dr. Ivano Gebhardt Rolf Gutz -  Full Professor (since 1992)",{"$nulls":13},"To read about the name, origins and customers of CurTiPot hold the mouse on the red marked cell Q34.",{"$nulls":20},"2. Click on the \"Tools\" tab"]
[" "," ",null,"Instituto de Química - Universidade de São Paulo, São Paulo, SP, Brazil",{"$nulls":13},"Version 2, improved and adapted for titrations with coulometric generation of reactants, was released in 1992.",{"$nulls":20},"3. Select \"Macro\""]
[" "," ",null,"Member of the Editorial Boards of Talanta (2005-2007) and Electrochemistry Communications (2005 -->)",{"$nulls":13},"Version 3.0 for Excel, an evolution of the DOS version with added Regression module was released in 2006 (in Portuguese).",{"$nulls":20},"4. Select \"Security\""]
[" "," ",null,"Member of the Brazilian Academy of Sciences",{"$nulls":13},"Version 3.1 was the first release translated to English, launched on the internet in May 1st, 2006.",{"$nulls":20},"5. Select \"Security level\""]
[" "," ",null,"Honored with the National Order of Scientific Merit, Brazil, 2007",{"$nulls":13},"Version 3.2, released in December 2006, includes a separate pH_calc module with activity coefficient estimation.",{"$nulls":20},"6. Select \"Medium\""]
[{"$nulls":3},"Fellow of the International Union of Pure and Applied Chemistry",{"$nulls":13},"Version 3.3, January 2008, has a friendlier interface with the Database and includes logarithmic distribution diagram generation overlaid on the titration curve.",{"$nulls":20},"7. Open the CurTiPot file and enable the content"]
[{"$nulls":3},"Research interests, CV, publications, see: http://www.iq.usp.br/gutz and",{"$nulls":13},"Version 3.4, October 2008, extends Ionic strength and activity coefficient calculations to the Regression module (formerly available only in pH_calc)."]
[{"$nulls":3},"http://scholar.google.com.br/citations?user=qXFK1_YAAAAJ&hl=pt-BR",{"$nulls":13},"Version 3.5, Jan/Feb 2010, calculates Buffer Capacity (BC) and medium charge (zm) (pH_calc module) and plots BC and zm and finds the isoelectric point (Distribution module)."]
[null,"CurTiPot was written almost during weekends and holidays, in São Paulo and, sometimes, in Guaeca",{"$nulls":15},"Version 3.6, March 2012 - Inflections (endpoints) of real and simulated titrations are located automatically by the improved Evaluation module, with smoothing and interpolation. "]
[null,"a nice beach where I took some pictures; search Google for: guaeca panoramio gutz",{"$nulls":15},"Version 4.0, January 2014 - Titration module for students introduced, embracing visual and instrumental end point detection; activity calculation extended to Simulation module"]
[{"$nulls":17},"Version 4.1, February 2014 - Titration module now imports Indicator colors from Database; Distribution, Evaluation and Analysis modules import data also from Titration."]
[{"$nulls":17},"Versions 4.1.1 to 4.1.3, January 2015 minor corrections and improved comments on ionic strength calculations."]
[{"$nulls":17},"Version 4.2.0, February 2015 - Extended data weighting options in Regression; ionic strength effect correction added to Distribution."]
[{"$nulls":17},"Version  4.2.2, September 2015 - Cells to fill with concentrations of bases protoneted to neutrality are now underlined in green."]
[{"$nulls":17},"Version  4.2.3. March 2016 - Indicator colors are loaded in Titration (function missing in v. 4.2.2)"]
[{"$nulls":17},"CurTiPot has reached over one hundred countries and was used and cited in over fifty papers and thesis: http://scholar.google.com/scholar?hl=en-USR&as_sdt=0,5&q=curtipot"]
[{"$nulls":17},"People from over 200 universities and 100 companies dowloaded CurTiPot"]

{"sheet":"   pH_calc   ","index":1,"n_rows":51,"n_cols":33,"rows_kept":51,"hidden":true}
[null,"             pH Calculator",{"$nulls":5},"<--- read comment",null,null," pKas of the acids and bases in the solution",null,null,"Click on K2 to Q2; select acids/bases; click on J2; read M1",{"$nulls":3}," Overall protonation constants = bp = SKp (calculated by the program)",{"$nulls":7},"       pKas loaded from the Database "]
["  Solution composition - reagents added, in mol/L",{"$nulls":4}," Fill out concentrations; Enter; Click button B18.",{"$nulls":4},8,1,6,3,7,2,5,"             pKa(n) = -log Kd(HB-->B) = log Kp(1)",{"$nulls":9},"Click on J2 to use these pKas in the pH calculation"]
["Acid / Base\nProtonation",{"$f":"K3","v":"Phosphoric acid"},{"$f":"L3","v":"Acetic acid"},"HCl","Carbonic acid","Hydroxide ion","Ammonia","EDTA",null,"Acid / Base","Phosphoric acid","Acetic acid","HCl","Carbonic acid","Hydroxide ion","Ammonia","EDTA","Acid / Base",{"$f":"K3","v":"Phosphoric acid"},{"$f":"L3","v":"Acetic acid"},"HCl","Carbonic acid","Hydroxide ion","Ammonia","EDTA","Acid / Base",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,2))","v":"Phosphoric acid"},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,2))","v":"Acetic acid"},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,2))","v":"HCl"},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,2))","v":"Carbonic acid"},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,2))","v":"Hydroxide ion"},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,2))","v":"Ammonia"},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,2))","v":"EDTA"}]
["[B]",{"$nulls":8},"Charge of B",-3,-1,-1,-2,-1,0,-4,"Charge of B",{"$f":"K4","v":-3},-1,-1,-2,-1,0,-4,"Charge of  B",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,3))","v":-3},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,3))","v":-1},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,3))","v":-1},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,3))","v":-2},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,3))","v":-1},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,3))","v":0},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,3))","v":-4}]
["[HB]",0.0265,{"$nulls":7},"pKa1",2.148,4.757,{"v":-7,"d":"-7.000"},6.352,15.745,9.244,{"v":-0.21,"d":"-0.210"},"bp1",{"$f":"IF(K5=\"\",\"\",IF(K6=\"\",10^K5,(IF(K7=\"\",10^K6,(IF(K8=\"\",10^K7,(IF(K9=\"\",10^K8,(IF(K10=\"\",10^K9,10^K10))))))))))","v":{"v":2238721138568.3457,"d":"2.239E+12"}},{"v":57147.86366718673,"d":"5.715E+04"},{"v":1e-07,"d":"1.000E-07"},{"v":21330449131.465843,"d":"2.133E+10"},{"v":5559042572704029,"d":"5.559E+15"},{"v":1753880501.8417609,"d":"1.754E+09"},{"v":107151930523.76077,"d":"1.072E+11"},"pKa1 = logKpn",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,4))","v":2.148},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,4))","v":4.757},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,4))","v":{"v":-7,"d":"-7.000"}},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,4))","v":6.352},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,4))","v":15.745},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,4))","v":9.244},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,4))","v":{"v":-0.21,"d":"-0.210"}}]
["[H2B]",0.02,{"$nulls":7},"pKa2",7.199,"","",10.329,"","",{"v":1.5,"d":"1.500"},"bp2",{"$f":"IF(K6=\"\",\"\",IF(K7=\"\",S5*10^K5,(IF(K8=\"\",S5*10^K6,(IF(K9=\"\",S5*10^K7,(IF(K10=\"\",S5*10^K8,S5*10^K9))))))))","v":{"v":3.539973410834362E+19,"d":"3.540E+19"}},"","",{"v":4.7973344863669224E+16,"d":"4.797E+16"},"","",{"v":6.025595860743592e+17,"d":"6.026E+17"},"pKa2 = logKpn-1",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,5))","v":7.199},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,5))","v":10.329},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,5))","v":{"v":1.5,"d":"1.500"}}]
["[H3B]",{"$nulls":8},"pKa3",{"v":12.35,"d":"12.350"},"","","","","",{"v":2.21,"d":"2.210"},"bp3",{"$f":"IF(K7=\"\",\"\",IF(K8=\"\",S6*10^K5,(IF(K9=\"\",S6*10^K6,(IF(K10=\"\",S6*10^K7,S6*10^K8))))))","v":{"v":4.977370849789387e+21,"d":"4.977E+21"}},"","","","","",{"v":7.76247116628694e+20,"d":"7.762E+20"},"pKa3 = logKpn-2",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,6))","v":{"v":12.35,"d":"12.350"}},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,6))","v":{"v":2.21,"d":"2.210"}}]
["[H4B]",{"$nulls":8},"pKa4","","","","","","",{"v":3.11,"d":"3.110"},"bp4",{"$f":"IF(K8=\"\",\"\",IF(K9=\"\",S7*10^K5,(IF(K10=\"\",S7*10^K6,S7*10^K7))))","v":""},"","","","","",{"v":1.2589254117941712E+23,"d":"1.259E+23"},"pKa4 = logKpn-3",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,7))","v":{"v":3.11,"d":"3.110"}}]
["[H5B]",{"$nulls":7},"Total","pKa5","","","","","","",{"v":6.75,"d":"6.750"},"bp5",{"$f":"IF(K9=\"\",\"\",IF(K10=\"\",S8*10^K5,S8*10^K6))","v":""},"","","","","",{"v":3.981071705534987e+24,"d":"3.981E+24"},"pKa5 = logKpn-4",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,8))","v":{"v":6.75,"d":"6.750"}}]
["[H6B]",{"$nulls":7},"SS","pKa6","","","","","","",{"v":11.03,"d":"11.030"},"bp6",{"$f":"IF(K10=\"\",\"\",S9*10^K5)","v":""},"","","","","",{"v":2.4547089156850394E+24,"d":"2.455E+24"},"pKa6 = logKpn-5",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,9))","v":{"v":11.03,"d":"11.030"}}]
["S[HiB]",{"$f":"SUM(B4:B10)","v":0.0465},{"$f":"SUM(C4:C10)","v":0},0,0,0,0,0,{"$f":"SUM(B11:H11)","v":{"v":0.0465,"d":"4.650E-02"}},"Electrolyte","Na+","K+","Ca++","Cl-","NO3-","SO4=","ClO4-","Kw",{"$f":"10^-K13","v":{"v":1.0069316688518014E-14,"d":"1.01E-14"}},{"$nulls":6},"Temperature",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,10)=\"\",\"unknown\",VLOOKUP(K$2,Database!$B$22:$N$301,10))","v":{"v":25,"d":"25.0"}},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,10)=\"\",\"unknown\",VLOOKUP(L$2,Database!$B$22:$N$301,10))","v":{"v":25,"d":"25.0"}},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,10)=\"\",\"unknown\",VLOOKUP(M$2,Database!$B$22:$N$301,10))","v":{"v":25,"d":"25.0"}},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,10)=\"\",\"unknown\",VLOOKUP(N$2,Database!$B$22:$N$301,10))","v":{"v":25,"d":"25.0"}},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,10)=\"\",\"unknown\",VLOOKUP(O$2,Database!$B$22:$N$301,10))","v":{"v":25,"d":"25.0"}},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,10)=\"\",\"unknown\",VLOOKUP(P$2,Database!$B$22:$N$301,10))","v":{"v":25,"d":"25.0"}},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,10)=\"\",\"unknown\",VLOOKUP(Q$2,Database!$B$22:$N$301,10))","v":{"v":25,"d":"25.0"}}]
["S[H]",{"$f":"B5+2*B6+3*B7+4*B8+5*B9+6*B10","v":0.0665},{"$f":"C5+2*C6+3*C7+4*C8+5*C9+6*C10","v":0},{"$f":"D5+2*D6+3*D7+4*D8+5*D9+6*D10","v":0},0,{"$f":"F5+2*F6+3*F7+4*F8+5*F9+6*F10","v":0},0,0,{"$f":"SUM(B12:H12)","v":{"v":0.0665,"d":"6.650E-02"}},"Ion charge",1,1,2,-1,-1,-2,-1,{"$nulls":8},"Ionic strength",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,11)=\"\",\"unknown\",VLOOKUP(K$2,Database!$B$22:$N$301,11))","v":{"v":0,"d":"0.000"}},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,11)=\"\",\"unknown\",VLOOKUP(L$2,Database!$B$22:$N$301,11))","v":{"v":0,"d":"0.000"}},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,11)=\"\",\"unknown\",VLOOKUP(M$2,Database!$B$22:$N$301,11))","v":{"v":0,"d":"0.000"}},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,11)=\"\",\"unknown\",VLOOKUP(N$2,Database!$B$22:$N$301,11))","v":{"v":0,"d":"0.000"}},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,11)=\"\",\"unknown\",VLOOKUP(O$2,Database!$B$22:$N$301,11))","v":{"v":0,"d":"0.000"}},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,11)=\"\",\"unknown\",VLOOKUP(P$2,Database!$B$22:$N$301,11))","v":{"v":0,"d":"0.000"}},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,11)=\"\",\"unknown\",VLOOKUP(Q$2,Database!$B$22:$N$301,11))","v":{"v":0,"d":"0.000"}}]
["SziCi",{"$f":"K4*B4+(K4+1)*B5+(K4+2)*B6+(K4+3)*B7+(K4+4)*B8+(K4+5)*B9+(K4+6)*B10","v":-0.073},0,{"$f":"M4*D4+(M4+1)*D5+(M4+2)*D6+(M4+3)*D7+(M4+4)*D8+(M4+5)*D9+(M4+6)*D10","v":0},0,{"$f":"O4*F4+(O4+1)*F5+(O4+2)*F6+(O4+3)*F7+(O4+4)*F8+(O4+5)*F9+(O4+6)*F10","v":0},0,0,{"$f":"SUM(B13:H13)","v":-0.073},"pKw",13.997]
["Electrolyte",{"$f":"K11","v":"Na+"},{"$f":"L11","v":"K+"},"Ca++","Cl-","NO3-","SO4=","ClO4-",null," Davies equation parameters",{"$nulls":3},"Color  coding"]
["Ci (mol/L)",0.073,{"$nulls":7}," for activity coefficient estimation",{"$nulls":3},"D  o     n  o  t     c  h  a  n  g  e "]
["ziCi",{"$f":"B15*K12","v":0.073},0,0,0,0,0,0,{"$f":"SUM(B16:H16)","v":0.073},"A ",0.509,null,null," C h a n g e   c r i t e r i o u s l y"]
["Charge Balance",{"$f":"IF(I17=0,\"OK\", \"WARNING\")","v":"OK"},{"$f":"IF(I17<0,\"Add cations/Remove anions\", \"\")","v":""},null,{"$f":"IF(I17>0,\"Add anions/Remove cations\", \"\")","v":""},null,null,{"$f":"IF(I17=0,\"\",\"Unbalance\")","v":""},{"$f":"I13+I16","v":0},"b",{"v":0.3,"d":"0.300"},null,null,"Fill out, change or leave blank"]
[]
[]
[]
[]
["  Results at chemical equilibrium",{"$nulls":8},"   Stepwise apparent constants recalculated for I ",null,null,{"$f":"E26","v":{"v":0.09950075168278918,"d":"0.09950"}},{"$nulls":4},"    Overall apparent protonation constants recalculated for I",{"$nulls":4},{"$f":"$E$26","v":{"v":0.09950075168278918,"d":"0.09950"}},{"$nulls":3},"How to enable the macro-instructions in Excel 2013, 2010 and 2007"]
["pH",{"v":7.00061877027891,"d":"7.001"},"a H+",{"v":9.9857625427858334E-8,"d":"9.986E-08"},"a OH-",{"v":1.0083660260938211E-7,"d":"1.008E-07"},"pOH",{"v":6.996381795015164,"d":"6.996"},null,"Acid / Base",{"$f":"K3","v":"Phosphoric acid"},{"$f":"L3","v":"Acetic acid"},"HCl","Carbonic acid","Hydroxide ion","Ammonia","EDTA","Acid / Base",{"$f":"K3","v":"Phosphoric acid"},{"$f":"L3","v":"Acetic acid"},"HCl","Carbonic acid","Hydroxide ion","Ammonia","EDTA",null,"     Needless to say, CurTiPot, freely distributed by the author since 1992,"]
["p[H]",{"v":6.893756068311632,"d":"6.894"},"[H+]",{"v":1.2771559533761944E-7,"d":"1.277E-07"},"[OH-]",{"v":1.2896768581148085E-7,"d":"1.290E-07"},"p[OH]",{"v":6.889519093047886,"d":"6.890"},null,"Charge of B",{"$f":"K4","v":-3},-1,-1,-2,-1,0,-4,"Charge of B",{"$f":"K4","v":-3},-1,-1,-2,-1,0,-4,null,"     is trustworthy and contains no harmful code."]
["\"pH\"",{"v":7.321204173844308,"d":"7.321"},"\"[H+]\"",{"v":4.7730482670581822E-8,"d":"4.773E-08"},"\"[OH-]\"",{"v":2.1096169614329777E-7,"d":"2.110E-07"},"\"pOH\"",{"v":6.675796391449769,"d":"6.676"},null,"pK'an = logK'p1",{"v":11.708824286973341,"d":"11.709"},{"v":4.543274788185462,"d":"4.543"},{"v":-7.213725686642174,"d":"-7.214"},{"v":9.90154960928617,"d":"9.902"},{"v":15.531275231955648,"d":"15.531"},{"v":9.244000373335602,"d":"9.244"},{"v":9.315098794995553,"d":"9.315"},"b'p1",{"v":511474296994.56995,"d":"5.11E+11"},{"v":34936.11469467894,"d":"3.49E+04"},{"v":6.1132844611895118E-8,"d":"6.11E-08"},{"v":7971668115.020069,"d":"7.97E+09"},{"v":3398400857880251,"d":"3.40E+15"},{"v":1753880501.8417609,"d":"1.75E+09"},{"v":2065848260.415817,"d":"2.07E+09"},null,"     All macros are fully removed when closing the file."]
["g H+",{"v":0.7818749555516862,"d":"0.782"},"    Ionic strength (mol/L)     ",null,{"v":0.09950075168278918,"d":"0.099501"},null,"g OH-",{"v":0.7818749555516862,"d":"0.782"},null,"pK'an-1 = logK'p2",{"v":6.771549482875478,"d":"6.772"},null,null,{"v":6.138274852602414,"d":"6.138"},null,null,{"v":5.468824034959693,"d":"5.469"},"b'p2",{"v":3.022546726541886E+18,"d":"3.02E+18"},null,null,{"v":1.0960334637441574E+16,"d":"1.10E+16"},null,null,{"v":608026115083652.5,"d":"6.08E+14"}]
["   Buffer Capacity (Buffer Index, DC/DpH)",null,null,"mol.L-1.pH-1",{"v":0.02624798789792268,"d":"0.026248"},"     Buffer Strength",null,{"v":0.011399356765514707,"d":"0.011399"},null,"pK'an-2 = logK'p3",{"v":1.934274682816295,"d":"1.934"},{"$nulls":5},{"v":2.252549300367517,"d":"2.253"},"b'p3",{"v":2.59805073748844e+20,"d":"2.60E+20"},{"$nulls":5},{"v":1.0876056180387254E+17,"d":"1.09E+17"},null,"1. Open a new blank Excel spreadsheet "]
[" Mean charge (zm) and mean protonation (hm) of the equilibrium HiB  species at pH",{"$nulls":5},{"$f":"B23","v":{"v":7.00061877027891,"d":"7.001"}},null,null,"pK'an-3 = logK'p4",{"$nulls":6},{"v":1.786274676839048,"d":"1.786"},"b'p4",{"$nulls":6},{"v":6.648842524658556e+18,"d":"6.65E+18"},null,"2. Click on the File tab (or the Office button, in Windows XP)(top left corner)"]
["Acid / Base",{"$f":"K3","v":"Phosphoric acid"},"Acetic acid","HCl","Carbonic acid","Hydroxide ion","Ammonia","EDTA",null,"pK'an-4 = logK'p5",{"$nulls":6},{"v":1.500000060580204,"d":"1.500"},"b'p5",{"$nulls":6},{"v":2.1025486181705286E+20,"d":"2.10E+20"},null,"3. Click on \"Options\" (bottom left)"]
["zm",{"v":-1.5698924464219046,"d":"-1.570"},{"v":-0.995557933315949,"d":"-0.996"},{"v":-0.9999999999999922,"d":"-1.000"},{"v":-0.8515907136791272,"d":"-0.852"},{"v":-2.3039946617231521E-9,"d":"-0.000"},{"v":0.9955555139196808,"d":"0.996"},{"v":-2.9675419732131836,"d":"-2.968"},null,"pK'an-5 = logK'p6",{"$nulls":6},{"v":0.21372540393455688,"d":"0.214"},"b'p6",{"$nulls":6},{"v":3.4393109489974844E+20,"d":"3.44E+20"},null,"4. Click on \"Trust Center\" (bottom left)"]
["hm",{"v":1.4301075535780954,"d":"1.430"},{"v":0.004442066684050985,"d":"0.004"},{"v":7.807617635918784E-15,"d":"0.000"},{"v":1.1484092863208728,"d":"1.148"},{"v":0.9999999976960053,"d":"1.000"},{"v":0.9955555139196808,"d":"0.996"},{"v":1.0324580267868166,"d":"1.032"},null,"pK'w",{"v":13.783275161359517,"d":"13.78"},{"$nulls":6},"K'w",{"v":1.6471205867228278E-14,"d":"1.65E-14"},{"$nulls":7},"5. Click on \"Trust Center Settings\" (bottom right)"]
[" Equilibrium concentration of species, in mol/L",{"$nulls":8}," Activity coefficient (g) of species",{"$nulls":3},"for pH ",{"$f":"B23","v":{"v":7.00061877027891,"d":"7.001"}},"and I ",{"$f":"E26","v":{"v":0.09950075168278918,"d":"0.0995"}},{"$nulls":9},"6. Click on \"Macro Settings\""]
["Acid / Base protonation",{"$f":"K3","v":"Phosphoric acid"},"Acetic acid","HCl","Carbonic acid","Hydroxide ion","Ammonia","EDTA","[H+]","Acid / Base  protonation",{"$f":"K3","v":"Phosphoric acid"},"Acetic acid","HCl","Carbonic acid","Hydroxide ion","Ammonia","EDTA",{"$nulls":9},"7. Click on \"Disable macros with notification\""]
["[B]",{"v":4.0566581283886205E-7,"d":"4.057E-07"},{"$nulls":6},{"$f":"D24","v":{"v":1.2771559533761944E-7,"d":"1.28E-07"}},"g B",{"v":0.10920328961081206,"d":"0.109"},{"v":0.7818749555516862,"d":"0.782"},{"v":0.7818749555516862,"d":"0.782"},{"v":0.3737224690342116,"d":"0.374"},{"v":0.7818749555516862,"d":"0.782"},{"v":1,"d":"1.000"},{"v":0.01950728538403802,"d":"0.020"},{"$nulls":9},"8. Click OK; follow steps 1 to 8 only once on each computer"]
["[HB]",{"v":0.02649940698426825,"d":"2.650E-02"},{"$nulls":7},"g HB",{"v":0.3737224690342116,"d":"0.374"},{"v":1,"d":"1.000"},{"v":1,"d":"1.000"},{"v":0.7818749555516862,"d":"0.782"},{"v":1,"d":"1.000"},{"v":0.7818749555516862,"d":"0.782"},{"v":0.10920328961081206,"d":"0.109"},{"$nulls":9},"9. Open the CurTiPot file"]
["[H2B]",{"v":0.019999967792643555,"d":"2.000E-02"},{"$nulls":6},"[OH-]","g H2B",{"v":0.7818749555516862,"d":"0.782"},null,null,{"v":1,"d":"1.000"},null,null,{"v":0.3737224690342116,"d":"0.374"},{"$nulls":9},"10. When the \"Security warning\" shows up, click on it to enable content"]
["[H3B]",{"v":2.1955727535819438E-7,"d":"2.196E-07"},{"$nulls":6},{"$f":"F24","v":{"v":1.2896768581148085E-7,"d":"1.29E-07"}},"g H3B",{"v":1,"d":"1.000"},{"$nulls":5},{"v":0.7818749555516862,"d":"0.782"}]
["[H4B]",{"$nulls":8},"g H4B",{"$nulls":6},{"v":1,"d":"1.000"},{"$nulls":9},"How to enable macros in MS Excel 97-2003: "]
["[H5B]",{"$nulls":8},"g H5B",{"$nulls":6},{"v":0.7818749555516862,"d":"0.782"},{"$nulls":9},"1. Open a new blank Excel spreadsheet "]
["[H6B]",{"$nulls":7},"SS","g H6B",{"$nulls":6},{"v":0.3737224690342116,"d":"0.374"},{"$nulls":9},"2. Click on the \"Tools\" tab"]
["S[HiB]",{"$f":"B34+B35+B36+B37+B38+B39+B40","v":{"v":0.0465,"d":"4.650E-02"}},{"$f":"C34+C35+C36+C37+C38+C39+C40","v":{"v":0,"d":"0.000E+00"}},{"v":0,"d":"0.000E+00"},{"v":0,"d":"0.000E+00"},{"v":0,"d":"0.000E+00"},{"v":0,"d":"0.000E+00"},{"v":0,"d":"0.000E+00"},{"$f":"SUM(B41:H41)","v":{"v":0.0465,"d":"4.650E-02"}},{"$nulls":17},"3. Select \"Macro\""]
[" Species distribution (fractional composition, in %)",{"$nulls":3},"for pH",{"$f":"B23","v":{"v":7.00061877027891,"d":"7.001"}},"or p[H]=",{"$f":"$B$24","v":{"v":6.893756068311632,"d":"6.894"}},null,"Electrolyte",{"$f":"K11","v":"Na+"},"K+","Ca++","Cl-","NO3-","SO4=","ClO4-",{"$nulls":9},"4. Select \"Security\""]
["Acid / Base protonation",{"$f":"K3","v":"Phosphoric acid"},"Acetic acid","HCl","Carbonic acid","Hydroxide ion","Ammonia","EDTA",null,"gi",{"v":0.7818749555516862,"d":"0.782"},{"v":0.7818749555516862,"d":"0.782"},{"v":0.3737224690342116,"d":"0.374"},{"v":0.7818749555516862,"d":"0.782"},{"v":0.7818749555516862,"d":"0.782"},{"v":0.3737224690342116,"d":"0.374"},{"v":0.7818749555516862,"d":"0.782"},{"$nulls":9},"5. Select \"Security level\""]
["% B",{"v":8.7239959750292913E-4,"d":"0.00"},{"v":99.55579333159491,"d":"99.56"},{"v":99.99999999999922,"d":"100.00"},{"v":0.08348058255429254,"d":"0.08"},{"v":2.3039946304600247E-7,"d":"0.00"},{"v":0.44444860803191866,"d":"0.44"},{"v":0.36395539124081655,"d":"0.36"},{"$nulls":18},"6. Select \"Medium\""]
["% HB",{"v":56.98797200917903,"d":"56.99"},{"v":0.4442066684050985,"d":"0.44"},{"v":7.807617635918784e-13,"d":"0.00"},{"v":84.99211020280413,"d":"84.99"},{"v":99.99999976960054,"d":"100.00"},{"v":99.55555139196808,"d":"99.56"},{"v":96.02636900165545,"d":"96.03"},{"$nulls":18},"7. Open the CurTiPot file and enable the content"]
["% H2B",{"v":43.0106834250399,"d":"43.01"},null,null,{"v":14.924409214641587,"d":"14.92"},null,null,{"v":3.609593144928798,"d":"3.61"}]
["% H3B",{"v":4.7216618356600944E-4,"d":"0.00"},{"$nulls":5},{"v":8.24615310983685e-05,"d":"0.00"}]
["% H4B",{"$nulls":6},{"v":6.438281044884922e-10,"d":"0.00"}]
["% H5B",{"$nulls":6},{"v":2.600242559576343e-15,"d":"0.00"}]
["% H6B",{"$nulls":6},{"v":5.432293037739869e-22,"d":"0.00"}]
["% S[HiB]",{"$f":"B44+B45+B46+B47+B48+B49+B50","v":{"v":100.00000000000001,"d":"100.00"}},{"$f":"C44+C45+C46+C47+C48+C49+C50","v":{"v":100.00000000000001,"d":"100.00"}},{"v":100,"d":"100.00"},{"v":100,"d":"100.00"},{"v":100,"d":"100.00"},{"v":100,"d":"100.00"},{"v":99.99999999999999,"d":"100.00"}]

{"sheet":"Titration","index":2,"n_rows":81,"n_cols":39,"rows_kept":81,"hidden":true}
[null,null,"Manual Virtual Titrator with visual indicator",{"$nulls":4},"<--- read instructions",null,null," pKas of the acids and bases in the solution",null,null,"Click on K2 to Q2; select acids/bases; click on J2; read M1",{"$nulls":6},"          Overall protonation constants = bp = PKp (calculated by the program)",{"$nulls":6},"  pKa(n) = -log Kd(HB-->B) = log Kp(1)",{"$nulls":3},"       pKas loaded from the Database "]
["     Sample and titrant (standard) composition (concentrations in mol/L)",{"$nulls":9},6,3,1,260,2,7,103,null,"Titrant",null,null,"Titrand",{"$nulls":6},"Titrant",{"$nulls":3},"    Titrand","Click on J2 to use these pKas in the Simulation"]
["SAMPLE\nSpecies",{"$f":"K3","v":"HCl"},"Carbonic acid","Acetic acid","Phenol Red (pKa 7.7)","Ammonia","Hydroxide ion","Glycine",null,"Acid / Base","HCl","Carbonic acid","Acetic acid","Phenol Red (pKa 7.7)","Ammonia","Hydroxide ion","Glycine","Strong ACID","Strong BASE","Carbonic ac.","Acid / Base",{"$f":"IF(K3=\"\",\"\",K3)","v":"HCl"},"Carbonic acid","Acetic acid","Phenol Red (pKa 7.7)","Ammonia","Hydroxide ion","Glycine",{"$f":"R3","v":"Strong ACID"},{"$f":"S3","v":"Strong BASE"},{"$f":"T3","v":"Carbonic ac."},"Acid / Base",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,2))","v":"HCl"},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,2))","v":"Carbonic acid"},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,2))","v":"Acetic acid"},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,2))","v":"Phenol Red (pKa 7.7)"},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,2))","v":"Ammonia"},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,2))","v":"Hydroxide ion"},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,2))","v":"Glycine"}]
["[B]",{"$nulls":8},"Charge of B",-1,-2,-1,-2,0,-1,-1,-1,-1,-2,"Charge of B",-1,-2,-1,-2,0,-1,-1,-1,-1,-2,"Charge of  B",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,3))","v":-1},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,3))","v":-2},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,3))","v":-1},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,3))","v":-2},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,3))","v":0},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,3))","v":-1},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,3))","v":-1}]
["[HB]",null,null,0.1,{"$nulls":5},"pKa1",{"v":-7,"d":"-7.000"},6.352,4.757,{"v":1.2,"d":"1.200"},9.244,15.745,{"v":2.35,"d":"2.350"},-6,15.745,6.352,"bp1",{"$f":"IF(K5=\"\",\"\",IF(K6=\"\",10^K5,(IF(K7=\"\",10^K6,(IF(K8=\"\",10^K7,(IF(K9=\"\",10^K8,(IF(K10=\"\",10^K9,10^K10))))))))))","v":{"v":1e-07,"d":"1.000E-07"}},{"v":21330449131.465843,"d":"2.133E+10"},{"v":57147.86366718673,"d":"5.715E+04"},{"v":50118723.362727284,"d":"5.012E+07"},{"v":1753880501.8417609,"d":"1.754E+09"},{"v":5559042572704029,"d":"5.559E+15"},{"v":5997910762.555122,"d":"5.998E+09"},{"$f":"IF(R5=\"\",\"\",IF(R6=\"\",10^R5,10^R6))","v":{"v":1e-06,"d":"1.000E-06"}},{"$f":"IF(S5=\"\",\"\",IF(S6=\"\",10^S5,10^S6))","v":{"v":5559042572704029,"d":"5.559E+15"}},{"$f":"IF(T5=\"\",\"\",IF(T6=\"\",10^T5,10^T6))","v":{"v":21330449131.465843,"d":"2.133E+10"}},"pKa1 = logKpn",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,4))","v":{"v":-7,"d":"-7.000"}},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,4))","v":6.352},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,4))","v":4.757},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,4))","v":{"v":1.2,"d":"1.200"}},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,4))","v":9.244},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,4))","v":15.745},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,4))","v":{"v":2.35,"d":"2.350"}}]
["[H2B]",{"$nulls":3},5e-05,{"$nulls":4},"pKa2","",10.329,"",{"v":7.7,"d":"7.700"},"","",9.778,null,null,10.329,"bp2",{"$f":"IF(K6=\"\",\"\",IF(K7=\"\",V5*10^K5,(IF(K8=\"\",V5*10^K6,(IF(K9=\"\",V5*10^K7,(IF(K10=\"\",V5*10^K8,V5*10^K9))))))))","v":""},{"v":4.7973344863669224E+16,"d":"4.797E+16"},"",{"v":794328234.7242825,"d":"7.943E+08"},"","",{"v":1342764961137.871,"d":"1.343E+12"},{"$f":"IF(R6=\"\",\"\",AC5*10^R5)","v":""},{"$f":"IF(S6=\"\",\"\",AD5*10^S5)","v":""},{"$f":"IF(T6=\"\",\"\",AE5*10^T5)","v":{"v":4.7973344863669224E+16,"d":"4.797E+16"}},"pKa2 = logKpn-1",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,5))","v":10.329},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,5))","v":{"v":7.7,"d":"7.700"}},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,5))","v":9.778}]
["[H3B]",{"$nulls":8},"pKa3","","","","","","","",{"$nulls":3},"bp3",{"$f":"IF(K7=\"\",\"\",IF(K8=\"\",V6*10^K5,(IF(K9=\"\",V6*10^K6,(IF(K10=\"\",V6*10^K7,V6*10^K8))))))","v":""},"","","","","","",{"$nulls":3},"pKa3 = logKpn-2",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,6))","v":""}]
["[H4B]",{"$nulls":7},"Total","pKa4","","","","","","","",{"$nulls":3},"bp4",{"$f":"IF(K8=\"\",\"\",IF(K9=\"\",V7*10^K5,(IF(K10=\"\",V7*10^K6,V7*10^K7))))","v":""},"","","","","","",{"$nulls":3},"pKa4 = logKpn-3",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,7))","v":""}]
["[H5B]",{"$nulls":7},"Sample","pKa5","","","","","","","",{"$nulls":3},"bp5",{"$f":"IF(K9=\"\",\"\",IF(K10=\"\",V8*10^K5,V8*10^K6))","v":""},"","","","","","",{"$nulls":3},"pKa5 = logKpn-4",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,8))","v":""}]
["[H6B]",{"$nulls":7},"SS","pKa6","","","","","","","",{"$nulls":3},"bp6",{"$f":"IF(K10=\"\",\"\",V9*10^K5)","v":""},"","","","","","",{"$nulls":3},"pKa6 = logKpn-5",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,9))","v":""}]
["S[HiB]",{"$f":"SUM(B4:B10)","v":0},{"$f":"SUM(C4:C10)","v":0},0.1,5e-05,0,0,0,{"$f":"SUM(B11:H11)","v":{"v":0.10005,"d":"1.001E-01"}},"pKw",13.997," Remark: this virtual titrator calculates \"pH\" values disregarding ion-ion interactions (pH calculations are available in the Simulation or pH_calc modules).",{"$nulls":8},"Kw",{"$f":"10^-K11","v":{"v":1.0069316688518014E-14,"d":"1.007E-14"}},{"$nulls":9},"Indicator: pKa1 or 2",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$R$301,14)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$R$301,14))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$R$301,14)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$R$301,14))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$R$301,14)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$R$301,14))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$R$301,14)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$R$301,14))","v":{"v":7.7,"d":"7.700"}},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$R$301,14)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$R$301,14))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$R$301,14)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$R$301,14))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$R$301,14)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$R$301,14))","v":""}]
["S[H]",{"$f":"B5+2*B6+3*B7+4*B8+5*B9+6*B10","v":0},{"$f":"C5+2*C6+3*C7+4*C8+5*C9+6*C10","v":0},0.1,1E-4,0,0,0,{"$f":"SUM(B12:H12)","v":{"v":0.10010000000000001,"d":"1.001E-01"}},{"$nulls":4},"Color  coding",{"$nulls":17},"color #, pH < pKa indic",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$R$301,15)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$R$301,15))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$R$301,15)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$R$301,15))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$R$301,15)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$R$301,15))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$R$301,15)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$R$301,15))","v":{"v":4907000,"d":"4907000.000"}},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$R$301,15)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$R$301,15))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$R$301,15)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$R$301,15))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$R$301,15)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$R$301,15))","v":""}]
["TITRANT",{"$f":"R3","v":"Strong ACID"},{"$f":"S3","v":"Strong BASE"},{"$f":"T3","v":"Carbonic ac."},"Total","  Volume of titrand in beaker (mL)",{"$nulls":7},"D  o     n  o  t     c  h  a  n  g  e ",{"$nulls":17},"color #, pH = pKa indic",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$R$301,16)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$R$301,16))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$R$301,16)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$R$301,16))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$R$301,16)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$R$301,16))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$R$301,16)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$R$301,16))","v":{"v":4961023,"d":"4961023.000"}},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$R$301,16)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$R$301,16))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$R$301,16)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$R$301,16))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$R$301,16)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$R$301,16))","v":""}]
["[B]",null,0.1,null,"Titrants","SAMPLE","Water","Sum",null,"           Titrant reservoir",{"$nulls":3}," C h a n g e   c r i t e r i o u s l y",{"$nulls":17},"color #, pH > pKa indic",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$R$301,17)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$R$301,17))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$R$301,17)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$R$301,17))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$R$301,17)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$R$301,17))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$R$301,17)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$R$301,17))","v":{"v":5263615,"d":"5263615.000"}},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$R$301,17)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$R$301,17))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$R$301,17)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$R$301,17))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$R$301,17)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$R$301,17))","v":""}]
["[HB]",{"$nulls":4},"Dispensed","added","(initial vol.)",null,"    Composition: cells B13 to D16",{"$nulls":3},"Fill out, change or leave blank"]
["[H2B]",{"$nulls":3},"SS",{"v":20,"d":"20.00"},{"v":0,"d":"0.00"},{"$f":"F16+G16","v":{"v":20,"d":"20.00"}}]
["S[HiB]",{"$f":"SUM(B14:B16)","v":0},{"$f":"SUM(C14:C16)","v":0.1},{"$f":"SUM(D14:D16)","v":0},{"$f":"SUM(B17:D17)","v":{"v":0.1,"d":"1.00E-01"}},"Buret (syringe) capacity"]
["S[H]",{"$f":"B15+2*B16","v":0},{"$f":"C15+2*C16","v":0},{"$f":"D15+2*D16","v":0},{"$f":"SUM(B18:D18)","v":{"v":0,"d":"0.00E+00"}},{"v":50,"d":"50.00"},null," mL of titrant                  ."]
["  Unknown sample"]
["Digital BURET"," motor",{"$f":"B21","v":{"v":27.910000000000014,"d":"28"}},{"$nulls":3},"pH-meter"]
["Volume, mL",{"v":27.910000000000014,"d":"27.910"},"Syringe with titrant",null,null,"\"pH\"  ",{"v":12.21319927694276,"d":"12.213"}]
[null,"Titrant addition (mL)    "]
[]
[{"$nulls":6},"Display (or hide)"]
[{"$nulls":5},true,"pH and titration curve"]
[{"$nulls":5},true,"Titrand equilibrium"]
[]
["  Model INDICATOR",{"$nulls":5}," TITRAND equilibrium"]
["pKa, indicator",{"v":7.7,"d":"7.700"},{"$nulls":4},"Molar fraction","Acetic acid"]
["Region","Color",{"$nulls":4},"% B",{"v":99.99999650215382,"d":"100.00"}]
["pH > pK+1",{"$f":"B29+1","v":{"v":8.7,"d":"8.700"}},null,{"v":12.21319927694276,"d":"12.213"},{"$f":"$D$31","v":{"v":12.21319927694276,"d":"12.213"}},null,"% HB",{"v":3.4978461854644776E-6,"d":"0.00"}]
["pH = pK",{"$f":"B29","v":7.7},null,{"$f":"$D$31","v":{"v":12.21319927694276,"d":"12.213"}},{"$f":"$D$31","v":{"v":12.21319927694276,"d":"12.213"}},null,"% H2B"]
["pH < pK-1",{"$f":"B29-1","v":{"v":6.7,"d":"6.700"}},null,{"$f":"$D$31","v":{"v":12.21319927694276,"d":"12.213"}},{"$f":"$D$31","v":{"v":12.21319927694276,"d":"12.213"}},null,"% H3B"]
["  INDICATOR equilibrium",null,null,{"$f":"$D$31","v":{"v":12.21319927694276,"d":"12.213"}},{"$f":"$D$31","v":{"v":12.21319927694276,"d":"12.213"}},null,"% H4B",{"$nulls":10}," Data ID on curves"]
["Molar fraction","Indicator",null,{"$f":"$D$31","v":{"v":12.21319927694276,"d":"12.213"}},{"$f":"$D$31","v":{"v":12.21319927694276,"d":"12.213"}},null,"% H5B",{"$nulls":10}," Copying curves"]
["% Ind",{"v":99.99693248001547,"d":"100.00"},null,"         Magnetic stirrer",null,null,"% H6B",{"$nulls":10}," Resizing axis"]
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[{"v":20.910000000000014,"d":"20.910"},{"v":11.334167880471796,"d":"11.334"},{"v":20.910000000000014,"d":"20.910"},{"v":11.334167880471796,"d":"11.334"},{"v":4.6326780474667635E-12,"d":"4.633E-12"},{"v":0.0489366903004059,"d":"4.894E-02"},{"v":0.48887802493277915,"d":"4.889E-01"},{"v":0.5111219750672209,"d":"5.111E-01"},null,null,{"v":2.6474758366316677E-7,"d":"0.0000"},{"v":2.3213001291864384E-4,"d":"0.0002"},{"$nulls":4},{"v":0.9999611714639514,"d":"1.0000"}]
[{"v":21.410000000000014,"d":"21.410"},{"v":11.522510181646794,"d":"11.523"},{"v":21.410000000000014,"d":"21.410"},{"v":11.522510181646794,"d":"11.523"},{"v":3.002547027998931e-12,"d":"3.003E-12"},{"v":0.048345810195814916,"d":"4.835E-02"},{"v":0.48297512678097065,"d":"4.830E-01"},{"v":0.5170248732190295,"d":"5.170E-01"},null,null,{"v":1.7158911895155093E-7,"d":"0.0000"},{"v":1.5046118208148166E-4,"d":"0.0002"},{"$nulls":4},{"v":0.9999400920908206,"d":"0.9999"}]
[{"v":21.910000000000014,"d":"21.910"},{"v":11.65073959948495,"d":"11.651"},{"v":21.910000000000014,"d":"21.910"},{"v":11.65073959948495,"d":"11.651"},{"v":2.2349118616824213E-12,"d":"2.235E-12"},{"v":0.047769028866014605,"d":"4.777E-02"},{"v":0.47721307563827237,"d":"4.772E-01"},{"v":0.5227869243617277,"d":"5.228E-01"},null,null,{"v":1.2772042193015224E-7,"d":"0.0000"},{"v":1.1199838418049014E-4,"d":"0.0001"},{"$nulls":4},{"v":0.9999195169094045,"d":"0.9999"}]
[{"v":22.910000000000014,"d":"22.910"},{"v":11.824925706256181,"d":"11.825"},{"v":22.910000000000014,"d":"22.910"},{"v":11.824925706256181,"d":"11.825"},{"v":1.4964916355317124E-12,"d":"1.496E-12"},{"v":0.046655791184622215,"d":"4.666E-02"},{"v":0.4660918200885573,"d":"4.661E-01"},{"v":0.5339081799114428,"d":"5.339E-01"},null,null,{"v":8.5521292560861439E-8,"d":"0.0000"},{"v":7.4996625303331275E-5,"d":"0.0001"},{"$nulls":4},{"v":0.999879808569224,"d":"0.9999"}]
[{"v":23.910000000000014,"d":"23.910"},{"v":11.943964170757681,"d":"11.944"},{"v":23.910000000000014,"d":"23.910"},{"v":11.943964170757681,"d":"11.944"},{"v":1.1377211438087334E-12,"d":"1.138E-12"},{"v":0.04559325892884727,"d":"4.559E-02"},{"v":0.45547711227510806,"d":"4.555E-01"},{"v":0.544522887724892,"d":"5.445E-01"},null,null,{"v":6.5018328520559654E-8,"d":"0.0000"},{"v":5.701787998737637E-5,"d":"0.0001"},{"$nulls":4},{"v":0.9998419132360189,"d":"0.9998"}]
[{"v":25.910000000000014,"d":"25.910"},{"v":12.104770549107343,"d":"12.105"},{"v":25.910000000000014,"d":"25.910"},{"v":12.104770549107343,"d":"12.105"},{"v":7.856506079256993e-13,"d":"7.857E-13"},{"v":0.04360705726251612,"d":"4.361E-02"},{"v":0.43563493792202124,"d":"4.356E-01"},{"v":0.5643650620779789,"d":"5.644E-01"},null,null,{"v":4.4898251767786113E-8,"d":"0.0000"},{"v":3.9374255044141682E-5,"d":"0.0000"},{"$nulls":4},{"v":0.9997710866492885,"d":"0.9998"}]
[{"v":27.910000000000014,"d":"27.910"},{"v":12.21319927694276,"d":"12.213"},{"v":27.910000000000014,"d":"27.910"},{"v":12.21319927694276,"d":"12.213"},{"v":6.12069477904589e-13,"d":"6.121E-13"},{"v":0.041786683339230156,"d":"4.179E-02"},{"v":0.4174493842621581,"d":"4.174E-01"},{"v":0.582550615737842,"d":"5.826E-01"},null,null,{"v":3.4978461817140012E-8,"d":"0.0000"},{"v":3.0675199812823656E-5,"d":"0.0000"},{"$nulls":4},{"v":0.9997061865605906,"d":"0.9997"}]

{"sheet":"Simulation","index":3,"n_rows":91,"n_cols":78,"rows_kept":91,"hidden":true}
[null,null,"  Virtual Titrator – Simulation of curves  ",{"$nulls":4},"<--- read instructions",null,null," pKas of the acids and bases in the solution",null,null,"Click on K2 to Q2; select acids/bases; click on J2; read M1",{"$nulls":6},"          Overall protonation constants = bp = PKp (calculated by the program)",{"$nulls":6},"  pKa(n) = -log Kd(HB-->B) = log Kp(1)",{"$nulls":3},"       pKas loaded from the Database "]
["     Titrand (sample) and titrant (standard) composition (concentrations in mol/L)",{"$nulls":9},5,8,98,1,2,6,3,null,"Titrant",null,null,"Titrand",{"$nulls":6},"Titrant",{"$nulls":3},"    Titrand","Click on J2 to use these pKas in the Simulation"]
["SAMPLE\nSpecies",{"$f":"K3","v":"EDTA"},{"$f":"L3","v":"Phosphoric acid"},"L-Glutamic acid ","Acetic acid","Ammonia","HCl","Carbonic acid",null,"Acid / Base","EDTA","Phosphoric acid","L-Glutamic acid ","Acetic acid","Ammonia","HCl","Carbonic acid","Strong ACID","Strong BASE","Carbonic ac.","Acid / Base",{"$f":"IF(K3=\"\",\"\",K3)","v":"EDTA"},"Phosphoric acid","L-Glutamic acid ","Acetic acid","Ammonia","HCl","Carbonic acid",{"$f":"R3","v":"Strong ACID"},{"$f":"S3","v":"Strong BASE"},{"$f":"T3","v":"Carbonic ac."},"Acid / Base",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,2))","v":"EDTA"},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,2))","v":"Phosphoric acid"},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,2))","v":"L-Glutamic acid "},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,2))","v":"Acetic acid"},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,2))","v":"Ammonia"},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,2))","v":"HCl"},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,2))","v":"Carbonic acid"}]
["[B]",{"$nulls":8},"Charge of B",-4,-3,-2,-1,0,-1,-2,-1,-1,-2,"Charge of B",-4,{"$f":"IF(L4=\"\",\"\",L4)","v":-3},-2,-1,0,-1,-2,-1,-1,-2,"Charge of  B",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,3))","v":-4},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,3))","v":-3},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,3))","v":-2},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,3))","v":-1},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,3))","v":0},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,3))","v":-1},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,3))","v":-2}]
["[HB]",{"$nulls":8},"pKa1",{"v":-0.21,"d":"-0.210"},2.148,{"v":2.23,"d":"2.230"},4.757,9.244,{"v":-7,"d":"-7.000"},6.352,-6,15.745,6.352,"bp1",{"$f":"IF(K5=\"\",\"\",IF(K6=\"\",10^K5,(IF(K7=\"\",10^K6,(IF(K8=\"\",10^K7,(IF(K9=\"\",10^K8,(IF(K10=\"\",10^K9,10^K10))))))))))","v":{"v":107151930523.76077,"d":"1.072E+11"}},{"v":2238721138568.3457,"d":"2.239E+12"},{"v":8912509381.337463,"d":"8.913E+09"},{"v":57147.86366718673,"d":"5.715E+04"},{"v":1753880501.8417609,"d":"1.754E+09"},{"v":1e-07,"d":"1.000E-07"},{"v":21330449131.465843,"d":"2.133E+10"},{"$f":"IF(R5=\"\",\"\",IF(R6=\"\",10^R5,10^R6))","v":{"v":1e-06,"d":"1.000E-06"}},{"$f":"IF(S5=\"\",\"\",IF(S6=\"\",10^S5,10^S6))","v":{"v":5559042572704029,"d":"5.559E+15"}},{"$f":"IF(T5=\"\",\"\",IF(T6=\"\",10^T5,10^T6))","v":{"v":21330449131.465843,"d":"2.133E+10"}},"pKa1 = logKpn",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,4))","v":{"v":-0.21,"d":"-0.210"}},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,4))","v":2.148},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,4))","v":{"v":2.23,"d":"2.230"}},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,4))","v":4.757},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,4))","v":9.244},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,4))","v":{"v":-7,"d":"-7.000"}},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,4))","v":6.352}]
["[H2B]",{"$nulls":8},"pKa2",{"v":1.5,"d":"1.500"},7.199,{"v":4.42,"d":"4.420"},"","","",10.329,null,null,10.329,"bp2",{"$f":"IF(K6=\"\",\"\",IF(K7=\"\",V5*10^K5,(IF(K8=\"\",V5*10^K6,(IF(K9=\"\",V5*10^K7,(IF(K10=\"\",V5*10^K8,V5*10^K9))))))))","v":{"v":6.025595860743592e+17,"d":"6.026E+17"}},{"v":3.539973410834362E+19,"d":"3.540E+19"},{"v":234422881531992.5,"d":"2.344E+14"},"","","",{"v":4.7973344863669224E+16,"d":"4.797E+16"},{"$f":"IF(R6=\"\",\"\",AC5*10^R5)","v":""},{"$f":"IF(S6=\"\",\"\",AD5*10^S5)","v":""},{"$f":"IF(T6=\"\",\"\",AE5*10^T5)","v":{"v":4.7973344863669224E+16,"d":"4.797E+16"}},"pKa2 = logKpn-1",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,5))","v":{"v":1.5,"d":"1.500"}},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,5))","v":7.199},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,5))","v":{"v":4.42,"d":"4.420"}},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,5))","v":10.329}]
["[H3B]",null,0.05,{"$nulls":6},"pKa3",{"v":2.21,"d":"2.210"},{"v":12.35,"d":"12.350"},{"v":9.95,"d":"9.950"},"","","","",{"$nulls":3},"bp3",{"$f":"IF(K7=\"\",\"\",IF(K8=\"\",V6*10^K5,(IF(K9=\"\",V6*10^K6,(IF(K10=\"\",V6*10^K7,V6*10^K8))))))","v":{"v":7.76247116628694e+20,"d":"7.762E+20"}},{"v":4.977370849789387e+21,"d":"4.977E+21"},{"v":3.981071705534978e+16,"d":"3.981E+16"},"","","","",{"$nulls":3},"pKa3 = logKpn-2",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,6))","v":{"v":2.21,"d":"2.210"}},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,6))","v":{"v":12.35,"d":"12.350"}},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,6))","v":{"v":9.95,"d":"9.950"}},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,6))","v":""}]
["[H4B]",{"$nulls":8},"pKa4",{"v":3.11,"d":"3.110"},"","","","","","",{"$nulls":3},"bp4",{"$f":"IF(K8=\"\",\"\",IF(K9=\"\",V7*10^K5,(IF(K10=\"\",V7*10^K6,V7*10^K7))))","v":{"v":1.2589254117941712E+23,"d":"1.259E+23"}},"","","","","","",{"$nulls":3},"pKa4 = logKpn-3",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,7))","v":{"v":3.11,"d":"3.110"}},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,7))","v":""}]
["[H5B]",{"$nulls":7},"Total","pKa5",{"v":6.75,"d":"6.750"},"","","","","","",{"$nulls":3},"bp5",{"$f":"IF(K9=\"\",\"\",IF(K10=\"\",V8*10^K5,V8*10^K6))","v":{"v":3.981071705534987e+24,"d":"3.981E+24"}},"","","","","","",{"$nulls":3},"pKa5 = logKpn-4",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,8))","v":{"v":6.75,"d":"6.750"}},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,8))","v":""}]
["[H6B]",{"$nulls":7},"SS","pKa6",{"v":11.03,"d":"11.030"},"","","","","","",{"$nulls":3},"bp6",{"$f":"IF(K10=\"\",\"\",V9*10^K5)","v":{"v":2.4547089156850394E+24,"d":"2.455E+24"}},"","","","","","",{"$nulls":3},"pKa6 = logKpn-5",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,9))","v":{"v":11.03,"d":"11.030"}},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,9))","v":""}]
["S[HiB]",{"$f":"SUM(B4:B10)","v":0},{"$f":"SUM(C4:C10)","v":0.05},0,0,0,0,0,{"$f":"SUM(B11:H11)","v":{"v":0.05,"d":"5.000E-02"}},"pKw",13.997,{"$nulls":9},"Kw",{"$f":"10^-K11","v":{"v":1.0069316688518014E-14,"d":"1.007E-14"}}]
["S[H]",{"$f":"B5+2*B6+3*B7+4*B8+5*B9+6*B10","v":0},{"$f":"C5+2*C6+3*C7+4*C8+5*C9+6*C10","v":0.15000000000000002},0,0,0,0,0,{"$f":"SUM(B12:H12)","v":{"v":0.15000000000000002,"d":"1.500E-01"}}]
["SziCi",{"$f":"K4*B4+(K4+1)*B5+(K4+2)*B6+(K4+3)*B7+(K4+4)*B8+(K4+5)*B9+(K4+6)*B10","v":0},{"$f":"L4*C4+(L4+1)*C5+(L4+2)*C6+(L4+3)*C7+(L4+4)*C8+(L4+5)*C9+(L4+6)*C10","v":0},0,0,0,0,0,{"$f":"SUM(B13:H13)","v":0}]
["TITRANT",{"$f":"R3","v":"Strong ACID"},{"$f":"S3","v":"Strong BASE"},{"$f":"T3","v":"Carbonic ac."},"Total",null,"Volume of titrand (in mL)",null,"  Counterions and other ions",null,{"$f":"IF(K17<>K16, \"error: K16><K17\",\"\")","v":""},{"$f":"IF(K20<>K19, \"error: K19><K20\",\"\")","v":""},"  Simulation of errors ",null," Davies equation parameters"]
["[B]",null,0.1,null,"Titrant(s)","SAMPLE","Water","Titrand","Sample (Titrand)","Minimum  (mol/L)","Extra in sample","Sum  (mol/L)","  (data dispersion)",null," for activity coefficient estimation"]
["[HB]",{"$nulls":4},"Dispensed","Added","Initial volume","Cations (monov.)",{"$f":"IF(I13<0,-I13,0)","v":0},0,{"$f":"J16+K16","v":0},"S pH=",{"v":0,"d":"0.000"},"A ",0.509]
["[H2B]",{"$nulls":3},"SS",20,0,{"$f":"F17+G17","v":{"v":20,"d":"20.00"}},"Anions (monov.)",{"$f":"IF(I13>0,I13,0)","v":0},0,{"$f":"J17+K17","v":0},"S Vol=",{"v":0,"d":"0.000"},"b",{"v":0.3,"d":"0.300"}]
["S[HiB]",{"$f":"SUM(B15:B17)","v":0},{"$f":"SUM(C15:C17)","v":0.1},{"$f":"SUM(D15:D17)","v":0},{"$f":"SUM(B18:D18)","v":{"v":0.1,"d":"1.00E-01"}},null,"Maximum titrant volume & additions ",null,"     Titrant","Minimum  (mol/L)","Extra  (mol/L)","Sum  (mol/L)","    Titration speed"]
["S[H]",{"$f":"B16+2*B17","v":0},{"$f":"C16+2*C17","v":0},{"$f":"D16+2*D17","v":0},{"$f":"SUM(B19:D19)","v":{"v":0,"d":"0.00E+00"}},"Titrant Vol.","Number of additions ",null,"Cations (monov.)",{"$f":"IF(E20<0,-E20,0)","v":0.1},0,{"$f":"J19+K19","v":0.1},"  Slower",0]
["SziCi",{"$f":"R4*B15+(R4+1)*B16+(R4+2)*B17","v":0},{"$f":"S4*C15+(S4+1)*C16+(S4+2)*C17","v":-0.1},{"$f":"T4*D15+(T4+1)*D16+(T4+2)*D17","v":0},{"$f":"SUM(B20:D20)","v":-0.1},{"v":50,"d":"50.00"},50,"Upper limits","Anions (monov.)",{"$f":"IF(E20>0,E20,0)","v":0},0,{"$f":"J20+K20","v":0},"  Faster","delay (s)    "]
[2]
[" ",{"$nulls":13},"Color  coding"]
[{"$nulls":14},"D  o     n  o  t     c  h  a  n  g  e "]
[{"$nulls":14}," C h a n g e   c r i t e r i o u s l y"]
[{"$nulls":14},"Fill out, change or leave blank"]
{"$rows_empty":8}
[" Data ID on curves"]
[" Copying curves"]
[" Resizing axis"]
[" Other graphics"]
[" Data analysis",{"$nulls":51},"Retained formed curves  "]
["Vadd",{"$f":"IF(A21=2,\"pH\", \"'pH'\")","v":"pH"},"Vadd",{"$f":"IF(A21=2,\"pH\", \"'pH'\")","v":"pH"},"[H]","CHtot =","Dil. factor","Dil. Factor","h1","h2","h3","h4","h5","h6","h7","h1 titrant","h2 titrant","h3 titrant","Parameters calculated only for the 'Activities, plot pH' option",{"$nulls":33},"Vol","pH","Vol","pH","Vol","pH","Vol","pH","Vol","pH","Vol","pH","Vol","pH","Vol","pH","Vol","pH","Vol","pH","Vol","pH","Vol","pH","Vol","pH"]
["(mL)","simulated","with \"error\" \n(do not use)","simulated with \"error\"",null,"CHcalc","Titrand (sample)","Titrant (buret)",{"$f":"K3","v":"EDTA"},"Phosphoric acid","L-Glutamic acid ","Acetic acid","Ammonia","HCl","Carbonic acid","Strong ACID","Strong BASE","Carbonic ac.","Ionic strength, I","I of counter- and extra ions","gH+","pH",{"$nulls":30},1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13]
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[null,"         Distribution Diagrams, Buffer Capacity and Protonation Curves",{"$nulls":5},"<--- read comment",{"$nulls":17},"Do not change or delete"]
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[{"$nulls":16},"Concentration of titrant (in the buret)  ",0.1,"  mol/L",{"v":4.230333333333333,"d":"4.2303"},{"v":3.9919723816354824,"d":"3.9920"},{"v":0.9537551640915823,"d":"0.9538"},{"v":0.3309176067469691,"d":"0.3309"}]
[{"$nulls":16},"  Number of mols of titrant",null,"Result (mol/L)",{"v":4.326666666666666,"d":"4.3267"},{"v":4.08694233579711,"d":"4.0869"},{"v":1.0182494746987578,"d":"1.0182"},{"v":0.33856592294072424,"d":"0.3386"}]
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[{"$nulls":14},"Results of the Example: ",{"$nulls":4},{"v":5.482666666666667,"d":"5.4827"},{"v":5.564549136468528,"d":"5.5645"},{"v":1.264938936848354,"d":"1.2649"},{"v":-0.285965430045119,"d":"-0.2860"}]
[{"$nulls":14},"[H3PO4] =  0,0501 mol/L in the 20 mL of sample",{"$nulls":4},{"v":5.579000000000001,"d":"5.5790"},{"v":5.683592463875255,"d":"5.6836"},{"v":1.205136344120432,"d":"1.2051"},{"v":-0.33070798287853254,"d":"-0.3307"}]
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[{"$nulls":14},"For this sample, half of the determined H2PO4- came from the H3PO4",{"$nulls":4},{"v":5.7716666666666665,"d":"5.7717"},{"v":5.902534491483016,"d":"5.9025"},{"v":1.0630081410083534,"d":"1.0630"},{"v":-0.390095302715409,"d":"-0.3901"}]
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[{"$nulls":15},"How to change the axis of a curve",{"$nulls":3},{"v":5.964333333333334,"d":"5.9643"},{"v":6.0934016405482545,"d":"6.0934"},{"v":0.9210133351249478,"d":"0.9210"},{"v":-0.34692355309037815,"d":"-0.3469"}]
[{"$nulls":15},"How to copy/paste a curve",{"$nulls":3},{"v":6.060666666666666,"d":"6.0607"},{"v":6.1789764288046385,"d":"6.1790"},{"v":0.8562542545909123,"d":"0.8563"},{"v":-0.3253376304245612,"d":"-0.3253"}]
[{"$nulls":15},"Data ID on curves",{"$nulls":3},{"v":6.157,"d":"6.1570"},{"v":6.258512878113957,"d":"6.2585"},{"v":0.795654055655842,"d":"0.7957"},{"v":-0.30375180346592345,"d":"-0.3038"}]
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[{"$nulls":14},"Results of the Example: ",{"$nulls":4},{"v":5.482666666666667,"d":"5.4827"},{"v":5.545670633288427,"d":"5.5457"},{"v":1.3072994883531743,"d":"1.3073"},{"v":-0.2788227617451619,"d":"-0.2788"}]
[{"$nulls":14},"[H3PO4] =  0,0501 mol/L in the 20 mL of sample",{"$nulls":4},{"v":5.579000000000001,"d":"5.5790"},{"v":5.668863874432608,"d":"5.6689"},{"v":1.2486431517256702,"d":"1.2486"},{"v":-0.3300153459975798,"d":"-0.3300"}]
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[{"$nulls":14},"For this sample, half of the determined H2PO4- came from the H3PO4",{"$nulls":4},{"v":5.7716666666666665,"d":"5.7717"},{"v":5.895925135121019,"d":"5.8959"},{"v":1.1018443300918934,"d":"1.1018"},{"v":-0.4236313889452323,"d":"-0.4236"}]
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[{"$nulls":19},{"v":29.662333333333333,"d":"29.6623"},{"v":11.549691554987014,"d":"11.5497"},{"v":0.01947298630533825,"d":"0.0195"},{"v":-8.2232086347169744E-4,"d":"-0.0008"}]
[{"$nulls":19},{"v":29.758666666666667,"d":"29.7587"},{"v":11.551559978200082,"d":"11.5516"},{"v":0.019319206645052236,"d":"0.0193"},{"v":-7.7398845705548989E-4,"d":"-0.0008"}]
[{"$nulls":19},{"v":29.855,"d":"29.8550"},{"v":11.553414035783991,"d":"11.5534"},{"v":0.019174747270946892,"d":"0.0192"},{"v":-7.25560342883836E-4,"d":"-0.0007"}]
[{"$nulls":19},{"v":29.951333333333334,"d":"29.9513"},{"v":11.555254625590564,"d":"11.5553"},{"v":0.019039608146142837,"d":"0.0190"},{"v":-6.7722793644962094E-4,"d":"-0.0007"}]
[{"$nulls":19},{"v":30.047666666666668,"d":"30.0477"},{"v":11.557082645471624,"d":"11.5571"},{"v":0.018913789270640066,"d":"0.0189"},{"v":-6.28895530015406E-4,"d":"-0.0006"}]
[{"$nulls":19},{"v":30.144000000000002,"d":"30.1440"},{"v":11.55889899327899,"d":"11.5589"},{"v":0.01879729068131796,"d":"0.0188"},{"v":-5.8037170812432078E-4,"d":"-0.0006"}]
[{"$nulls":19},{"v":30.240333333333332,"d":"30.2403"},{"v":11.56070456686449,"d":"11.5607"},{"v":0.018690112322857458,"d":"0.0187"},{"v":-5.3213500942754456E-4,"d":"-0.0005"}]
[{"$nulls":19},{"v":30.336666666666666,"d":"30.3367"},{"v":11.562500264079944,"d":"11.5625"},{"v":0.01859225423213793,"d":"0.0186"},{"v":-4.8380260299332956E-4,"d":"-0.0005"}]
[{"$nulls":19},{"v":30.433,"d":"30.4330"},{"v":11.56428698277717,"d":"11.5643"},{"v":0.01850371642759907,"d":"0.0185"},{"v":-4.3527878108423683E-4,"d":"-0.0004"}]
[{"$nulls":19},{"v":30.529333333333334,"d":"30.5293"},{"v":11.566065620807999,"d":"11.5661"},{"v":0.018424498853921806,"d":"0.0184"},{"v":-3.8704208238746061E-4,"d":"-0.0004"}]
[{"$nulls":19},{"v":30.625666666666667,"d":"30.6257"},{"v":11.567837076024245,"d":"11.5678"},{"v":0.01835460156642521,"d":"0.0184"},{"v":-3.3861396823381423E-4,"d":"-0.0003"}]
[{"$nulls":19},{"v":30.722,"d":"30.7220"},{"v":11.569602246277736,"d":"11.5696"},{"v":0.018294024528229903,"d":"0.0183"},{"v":-2.9018585406216039E-4,"d":"-0.0003"}]
[{"$nulls":19},{"v":30.818333333333335,"d":"30.8183"},{"v":11.571362029420293,"d":"11.5714"},{"v":0.01824276775777557,"d":"0.0182"},{"v":-2.4185344762794533E-4,"d":"-0.0002"}]
[{"$nulls":19},{"v":30.91466666666667,"d":"30.9147"},{"v":11.573117323303737,"d":"11.5731"},{"v":0.018200831236622528,"d":"0.0182"},{"v":-1.935210411937303E-4,"d":"-0.0002"}]
[{"$nulls":19},{"v":31.011,"d":"31.0110"},{"v":11.574869025779892,"d":"11.5749"},{"v":0.018168214983210463,"d":"0.0182"},{"v":-1.4509292702207644E-4,"d":"-0.0001"}]
[{"$nulls":19},{"v":31.107333333333333,"d":"31.1073"},{"v":11.576618034700578,"d":"11.5766"},{"v":0.018144918997539373,"d":"0.0181"},{"v":-9.6664812868430059E-5,"d":"-0.0001"}]
[{"$nulls":19},{"v":31.203666666666667,"d":"31.2037"},{"v":11.57836524791762,"d":"11.5784"},{"v":0.018130943261169572,"d":"0.0181"},{"v":-4.833240643421503E-5,"d":"-0.0000"}]
[{"$nulls":19},{"v":31.3,"d":"31.3000"},{"v":11.580111563282841,"d":"11.5801"},{"v":0.01812628777410106,"d":"0.0181"},{"v":-9.5707737438852625E-8,"d":"-0.0000"}]

{"sheet":"Regression","index":7,"n_rows":162,"n_cols":49,"rows_kept":162,"hidden":true}
[null,"          Titration Data Analysis - Multiple Regression",{"$nulls":4},"<--- read important remarks and instructions",{"$nulls":3}," pKas of the acids and bases in the solution",null,null,"Click on K2 to Q2; select acids/bases; click on J2; other options, read M1",{"$nulls":6},"          Overall protonation constants = bp = PKp (calculated by the program)",{"$nulls":10},"       pKas loaded from the Database ",{"$nulls":9},"Besides enabled macros, the Regression module also requires the Solver,"]
["     Composition of the sample (regression fit, in blue, and equilibrium at initial pH) and of the titrant; all concentrations in mol/L",{"$nulls":9},62,103,31,1,2,3,6,null,"Titrant",null,null,"Titrand",{"$nulls":6},"Titrant",{"$nulls":3},"    Titrand","Click on J2 to use these pKas in the Regression",{"$nulls":7},"an Add-In supplement provided by Microsoft with the Office package"]
["SAMPLE \nSpecies",{"$f":"K3","v":"Citric acid"},{"$f":"L3","v":"Glycine"},"Ascorbic acid ","Acetic acid","Ammonia","Carbonic acid","HCl",null,"Acid / Base","Citric acid","Glycine","Ascorbic acid ","Acetic acid","Ammonia","Carbonic acid","HCl","Strong ACID","Strong BASE","Carbonic ac.","Acid / Base",{"$f":"K3","v":"Citric acid"},"Glycine","Ascorbic acid ","Acetic acid","Ammonia","Carbonic acid","HCl","Strong ACID","Strong BASE","Carbonic ac.","Acid / Base",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,2))","v":"Citric acid"},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,2))","v":"Glycine"},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,2))","v":"Ascorbic acid "},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,2))","v":"Acetic acid"},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,2))","v":"Ammonia"},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,2))","v":"Carbonic acid"},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,2)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,2))","v":"HCl"},null,null,"If not already installed, follow the instructions (may change a bit, for different Excel versions)"]
["[B]",{"$f":"IF(K5=\"\",0,(B$11)/M$41)","v":1.2099340361430618E-7},4.27751853985554e-09,0,0,0,{"$f":"IF(P5=\"\",0,(G$11)/R$41)","v":0},0,null,"Charge of B",-3,-1,-2,-1,0,-2,-1,-1,-1,-2,"Charge of B",{"$f":"K4","v":-3},-1,-2,-1,0,-2,-1,-1,-1,-2,"Charge of  B",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,3))","v":-3},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,3))","v":-1},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,3))","v":-2},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,3))","v":-1},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,3))","v":0},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,3))","v":-2},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,3)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,3))","v":-1},null,null,"1. Open a new blank Excel spreadsheet "]
["[HB]",{"$f":"IF(K5=\"\",0,(B$11*(V$5*$AU41^(-2*V$4))*$D41)/M$41)","v":2.0778132559435929E-4},0.027137463866597454,0,0,0,0,0,null,"pKa1",3.128,{"v":2.35,"d":"2.350"},{"v":4.1,"d":"4.100"},4.757,9.244,6.352,{"v":-7,"d":"-7.000"},-7,15.745,6.352,"bp1",{"$f":"IF(K5=\"\",\"1E-10\",IF(K6=\"\",10^K5,(IF(K7=\"\",10^K6,(IF(K8=\"\",10^K7,(IF(K9=\"\",10^K8,(IF(K10=\"\",10^K9,10^K10))))))))))","v":{"v":2488857.318282395,"d":"2.489E+06"}},{"v":5997910762.555122,"d":"5.998E+09"},{"v":616595001861.4828,"d":"6.166E+11"},{"v":57147.86366718673,"d":"5.715E+04"},{"v":1753880501.8417609,"d":"1.754E+09"},{"v":21330449131.465843,"d":"2.133E+10"},{"v":1e-07,"d":"1.000E-07"},{"$f":"IF(R5=\"\",\"1E-10\",IF(R6=\"\",10^R5,(IF(R7=\"\",10^R6))))","v":{"v":1e-07,"d":"1.000E-07"}},{"$f":"IF(S5=\"\",\"1E-10\",IF(S6=\"\",10^S5,(IF(S7=\"\",10^S6))))","v":{"v":5559042572704029,"d":"5.559E+15"}},{"$f":"IF(T5=\"\",\"1E-10\",IF(T6=\"\",10^T5,(IF(T7=\"\",10^T6))))","v":{"v":21330449131.465843,"d":"2.133E+10"}},"pKa1 = logKpn",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,4))","v":3.128},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,4))","v":{"v":2.35,"d":"2.350"}},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,4))","v":{"v":4.1,"d":"4.100"}},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,4))","v":4.757},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,4))","v":9.244},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,4))","v":6.352},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,4)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,4))","v":{"v":-7,"d":"-7.000"}}]
["[H2B]",{"$f":"IF(K6=\"\",0,(B$11*(V$6*$AU41^(-4*V$4-2))*$D41^2)/M$41)","v":0.010238058360396924},7.95633178569774E-3,0,0,0,0,0,null,"pKa2",4.761,9.778,{"v":11.79,"d":"11.790"},"","",10.329,"",null,null,10.329,"bp2",{"$f":"IF(K6=\"\",\"10E-10\",IF(K7=\"\",V5*10^K5,(IF(K8=\"\",V5*10^K6,(IF(K9=\"\",V5*10^K7,(IF(K10=\"\",V5*10^K8,V5*10^K9))))))))","v":{"v":143548943335.36603,"d":"1.435E+11"}},{"$f":"IF(L6=\"\",\"1E-10\",IF(L7=\"\",W5*10^L5,(IF(L8=\"\",W5*10^L6,(IF(L9=\"\",W5*10^L7,(IF(L10=\"\",W5*10^L8,W5*10^L9))))))))","v":{"v":1342764961137.871,"d":"1.343E+12"}},{"v":7762471166286925,"d":"7.762E+15"},"1E-10","1E-10",{"v":4.7973344863669224E+16,"d":"4.797E+16"},"1E-10",{"$f":"IF(R6=\"\",\"1E-10\",IF(R7=\"\",AC5*10^R5))","v":"1E-10"},{"$f":"IF(S6=\"\",\"1E-10\",IF(S7=\"\",AD5*10^S5))","v":"1E-10"},{"$f":"IF(T6=\"\",\"1E-10\",IF(T7=\"\",AE5*10^T5))","v":{"v":4.7973344863669224E+16,"d":"4.797E+16"}},"pKa2 = logKpn-1",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,5))","v":4.761},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,5))","v":9.778},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,5))","v":{"v":11.79,"d":"11.790"}},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,5))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,5))","v":10.329},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,5)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,5))","v":""},null,null,"2. Click on the File tab (or the Office button, in Windows XP)(top left corner)"]
["[H3B]",{"$f":"IF(K7=\"\",0,(B$11*(V$7*$AU41^(-6*V$4-6))*$D41^3)/M$41)","v":0.014541022903171512},0,0,0,0,0,0,null,"pKa3",6.396,"","","","","","",{"$nulls":3},"bp3",{"$f":"IF(K7=\"\",\"1E-10\",IF(K8=\"\",V6*10^K5,(IF(K9=\"\",V6*10^K6,(IF(K10=\"\",V6*10^K7,V6*10^K8))))))","v":{"v":192752491319094.3,"d":"1.928E+14"}},"1E-10","1E-10","1E-10","1E-10","1E-10","1E-10",{"$nulls":3},"pKa3 = logKpn-2",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,6))","v":6.396},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,6))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,6)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,6))","v":""}]
["[H4B]",{"$f":"IF(K8=\"\",0,(B$11*(V$8*$AU41^(-8*V$4-12))*$D41^4)/M$41)","v":0},0,0,0,0,0,0,null,"pKa4","","","","","","","","pKw",null,null,"bp4",{"$f":"IF(K8=\"\",\"1E-10\",IF(K9=\"\",V7*10^K5,(IF(K10=\"\",V7*10^K6,V7*10^K7))))","v":"1E-10"},"1E-10","1E-10","1E-10","1E-10","1E-10","1E-10","Kw",null,null,"pKa4 = logKpn-3",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,7))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,7)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,7))","v":""},null,null,"3. Click on \"Options\" (bottom left)",{"$nulls":3},"Window for Mac:  skip step 2, click \"Tools\""]
["[H5B]",{"$f":"IF(K9=\"\",0,(B$11*(V$9*$AU41^(-10*V$4-20))*$D41^5)/M$41)","v":0},0,0,0,0,0,0,"Total","pKa5","","","","","","","",{"v":13.997,"d":"13.9970"},null,null,"bp5",{"$f":"IF(K9=\"\",\"1E-10\",IF(K10=\"\",V8*10^K5,V8*10^K6))","v":"1E-10"},"1E-10","1E-10","1E-10","1E-10","1E-10","1E-10",{"$f":"10^-R9","v":{"v":1.0069316688518014E-14,"d":"1.01E-14"}},null,null,"pKa5 = logKpn-4",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,8))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,8)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,8))","v":""}]
["[H6B]",{"$f":"IF(K10=\"\",0,(B$11*(V$10*$AU41^(-12*V$4-30))*$D41^6)/M$41)","v":0},0,0,0,0,0,0,"SS","pKa6","","","","","","","",{"$nulls":3},"bp6",{"$f":"IF(K10=\"\",\"1E-10\",V9*10^K5)","v":"1E-10"},"1E-10","1E-10","1E-10","1E-10","1E-10","1E-10",{"$nulls":3},"pKa6 = logKpn-5",{"$f":"IF(VLOOKUP(K$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(K$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(L$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(L$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(M$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(M$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(N$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(N$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(O$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(O$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(P$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(P$2,Database!$B$22:$N$301,9))","v":""},{"$f":"IF(VLOOKUP(Q$2,Database!$B$22:$N$301,9)=\"\",\"\",VLOOKUP(Q$2,Database!$B$22:$N$301,9))","v":""},null,null,"4. Click on \"Add-ins\" (bottom left)"]
["S[HiB]",0.02498698358256641,0.035093799929813735,0,0,0,0,0,{"$f":"SUM(B11:H11)","v":{"v":0.060080783512380144,"d":"6.008E-02"}},"SS[bases]","","","","  Correction of the pH sensor calibration",null,null,"        Ionic Strength, I (initial)",null,"Sample ions","Titrant ions",{"$nulls":4},"   Overall apparent constants recalculated for applied initial I =",{"$f":"AT41","v":{"v":0.010862132584639951,"d":"0.010862"}},"and g H+=",{"$f":"S23","v":{"v":0.8987043944350366,"d":"0.899"}},"recalc. for","g H+=",{"v":0.7815939439265172,"d":"0.782"}]
["S[H] bound",{"$f":"B5+2*B6+3*B7+4*B8+5*B9+6*B10","v":0.06430696675590275},0.043050127437992934,0,0,0,0,0,{"$f":"SUM(B12:H12)","v":{"v":0.10735709419389569,"d":"1.074E-01"}},"SS[H] bound",{"$nulls":3}," Intersection pH (may be fitted)",null,{"v":7,"d":"7.0000"},"Other ions","SCk(z=1)",{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},"bp1",{"$f":"IF(K5=\"\",\"\",(V5*$AB$11^(-2*V$4)))","v":{"v":1311297.374653342,"d":"1.31E+06"}},{"v":4844330117.913531,"d":"4.84E+09"},{"v":402223518878.192,"d":"4.02E+11"},{"v":46156.59153612238,"d":"4.62E+04"},{"v":1753880501.8417609,"d":"1.75E+09"},{"v":13914495386.775555,"d":"1.39E+10"},{"v":8.0766958857684576E-8,"d":"8.08E-08"},{"v":6.1088909318260758E-8,"d":"6.11E-08"},{"v":3395958476202674.5,"d":"3.40E+15"},{"v":7960213986.678303,"d":"7.96E+09"},{"$nulls":10},"5. Click on \"Solver\" in the Add-Ins list",{"$nulls":3},"Window for Mac:  check the Solver box; skip 6 na 7"]
["max. free H ",{"$f":"IF(K4=\"\",\"0\",(-K4*B11)-B12)","v":0.010653983991796484},{"$f":"IF(L4=\"\",\"0\",(-L4*C11)-C12)","v":-0.0079563275081792},0,0,0,0,0,{"$f":"SUM(B13:H13)","v":{"v":2.6976564836172848E-3,"d":"2.698E-03"}},"SS[H] max. free H+ ","(negative results are possible)",null,null," Slope (may be fitted, read comment)",null,{"v":1,"d":"100.00%"},"mol/L","SCk(z=2)",{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},"bp2",{"$f":"IF(K6=\"\",\"\",(V6*$AB$11^(-4*V$4-2)))","v":{"v":49336535904.71576,"d":"4.93E+10"}},{"$f":"IF(L6=\"\",\"\",(W6*$AB$11^(-4*W$4-2)))","v":{"v":1084510423717.6287,"d":"1.08E+12"}},{"v":4089791723456030,"d":"4.09E+15"},"","",{"v":2.5275583582461972E+16,"d":"2.53E+16"},"",null,null,{"v":1.0936720513474194E+16,"d":"1.09E+16"}]
["TITRANT",{"$f":"R3","v":"Strong ACID"},{"$f":"S3","v":"Strong BASE"},{"$f":"T3","v":"Carbonic ac."},null,"Volume of Titrand (mL)",null,"Sample",{"$f":"I18-(I12+I13)","v":{"v":1.4363439565651115E-5,"d":"1.436E-05"}},"Partial charge balance <--> counterions (opposite signal)",null,null,{"$f":"S15","v":{"v":1.3880415343291224E-3,"d":"1.388E-03"}},null," Davies equation parameters",null,"(z = ion charge)","1/2.SCkzk2 = Ik",{"$f":"0.5*(S12+S13*4)","v":{"v":0,"d":"0.000000"}},{"$f":"0.5*(T12+T13*4)","v":{"v":0,"d":"0.000000"}},"bp3",{"$f":"IF(K7=\"\",\"\",(V7*$AB$11^(-6*V$4-6)))","v":{"v":53505987458783.05,"d":"5.35E+13"}},{"$f":"IF(L7=\"\",\"\",(W7*$AB$11^(-6*W$4-6)))","v":""},"","","","","",{"$nulls":13},"6. Click on \"Go\" near the bottom of the page"]
["[B]",null,0.1,null,"SAMPLE","Water","Total","Titrand [H]=10-p[H]",{"$f":"D41","v":{"v":1.3096149588078488E-3,"d":"1.310E-03"}},{"$f":"-LOG10(I15)","v":{"v":2.882856372928276,"d":"2.883"}},"  initial p[H]",{"$nulls":3}," for activity coefficient estimation",null,"Minimum","SzjCj",{"$f":"-(S18/S17) - (G16/E16)*(S24- $AC$9/AU41^2/S24)","v":{"v":1.3880415343291224E-3,"d":"0.001388"}},{"$f":"-T18/T17 - (T24- $AC$9/AE11^2/T24)","v":{"v":0.10000000007858748,"d":"0.100000"}},"bp4",{"$f":"IF(K8=\"\",\"\",(V8*$AB$11^(-8*V$4-12)))","v":""},{"$f":"IF(L8=\"\",\"\",(W8*$AB$11^(-8*W$4-12)))","v":""},"","","","",""]
["[HB]",{"$nulls":3},20,0,{"$f":"E16+F16","v":{"v":20,"d":"20.00"}},"Titrand [OH]=Kw/[H]",{"$f":"AB21/I15","v":{"v":9.51968640834426e-12,"d":"9.520E-12"}},{"$f":"-LOG10(I16)","v":{"v":11.02137735764166,"d":"11.021"}},"  initial p[OH] for ionic strength, I",null,{"$f":"AT41","v":{"v":0.010862132584639951,"d":"0.010862"}},null,"A ",0.509,"of counter-ions","1/2.SCjzj2 = Ij",{"$f":"0.5*S17^2*ABS(S15)","v":{"v":6.9402076716456121E-4,"d":"0.000694"}},{"$f":"0.5*T17^2*ABS(T15)","v":{"v":0.05000000003929374,"d":"0.050000"}},"bp5",{"$f":"IF(K9=\"\",\"\",(V9*$AB$11^(-10*V$4-20)))","v":""},{"$f":"IF(L9=\"\",\"\",(W9*$AB$11^(-10*W$4-20)))","v":""},"","","","","",{"$nulls":13},"7. Check Solver add-in in the pop-on box "]
["[H2B]",{"$nulls":3},"SS",null,null,"Sample CHcalc",{"$f":"I12+ (G16/E16)*(I15-I16)","v":{"v":0.10866670914318385,"d":"1.087E-01"}},{"$nulls":5},"b",{"v":0.3,"d":"0.300"},"for acids/bases","Counterion charge",1,1,"bp6",{"$f":"IF(K10=\"\",\"\",(V10*$AB$11^(-12*V$4-30)))","v":""},{"$f":"IF(L10=\"\",\"\",(W10*$AB$11^(-12*W$4-30)))","v":""},"","","","",""]
["S[HiB]",{"$f":"B15+B16+B17","v":0},{"$f":"C15+C16+C17","v":0.1},{"$f":"D15+D16+D17","v":0},{"$f":"SUM(B18:D18)","v":0.1},"SS[HiB]",null,"Sample CHReg",{"v":0.11006911411707862,"d":"1.101E-01"},"<--- Find CHReg, concentrations (line 11, in blue) and pKas with Solver",{"$nulls":6},"Acid/base ions","SziCi",{"$f":"SUM(V18:AB18)","v":{"v":-2.6976564836172848E-3,"d":"-0.002698"}},{"$f":"SUM(AC18:AE18)","v":{"v":-1.7801328661559514E-4,"d":"-0.000178"}},"SziCi",{"$f":"K4*B4+(K4+1)*B5+(K4+2)*B6+(K4+3)*B7+(K4+4)*B8+(K4+5)*B9+(K4+6)*B10","v":{"v":-0.010653983991796486,"d":"-0.010654"}},{"v":7.956327508179201E-3,"d":"0.007956"},{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},{"v":-1.7801328661559514E-4,"d":"-0.000178"},{"v":0,"d":"0.000000"},{"$nulls":10},"8. Click OK; follow steps 1 to 8 only once on each computer"]
["S[H]",{"$f":"B16+2*B17","v":0},{"$f":"C16+2*C17","v":0},{"$f":"D16+2*D17","v":0},{"$f":"SUM(B19:D19)","v":0},"SS [H]          pH",{"v":12.889207394858074,"d":"12.889"},"S(|RCH|a×|RpH|b×|dpH|c)",{"$f":"SUM($G$41:$G$162)","v":{"v":1.0070398416075227E-5,"d":"1.007E-05"}},"<--- Minimize S of weighted residuals product with Solver",{"$nulls":6},"at given pH","1/2.SCizi2 = Ii",{"$f":"0.5*SUM(V19:AB19)","v":{"v":0.009513304333311583,"d":"0.009513"}},{"$f":"0.5*(SUM(AC19:AE19))","v":{"v":8.900664330779757E-5,"d":"0.000089"}},"Szi2Ci",{"$f":"V4^2*B4+(V4+1)^2*B5+(V4+2)^2*B6+(V4+3)^2*B7+(V4+4)^2*B8+(V4+5)^2*B9+(V4+6)^2*B10","v":{"v":0.01107027260340689,"d":"0.011070"}},{"v":0.007956336063216279,"d":"0.007956"},{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},{"v":0,"d":"0.000000"},{"v":1.7801328661559514E-4,"d":"0.000178"},{"v":0,"d":"0.000000"}]
[{"$nulls":7},"Weights: exponent a",{"v":2,"d":"2.000"},"exponent b   ",{"v":0,"d":"0.000"},"exponent c  ",{"v":0,"d":"0.000"},{"$nulls":3},"Total I ","I = Ii+Ij+Ik+IH+IOH",{"$f":"S19+S16+S14+0.5*S24+0.5*S25","v":{"v":0.010862132584639913,"d":"0.010862"}},{"$f":"T19+T16+T14+0.5*T24+0.5*T25","v":{"v":0.1000000000787526,"d":"0.100000"}},{"$nulls":7},"Kw","Kw",{"$nulls":12},"9. Open the CurTiPot file and click on the Regression lower tab"]
[{"$nulls":16},"Action","Parameter","Titrand","Titrant",{"$nulls":7},{"$f":"AC9/S23^2","v":{"v":1.2467123723527407E-14,"d":"1.247E-14"}},{"$f":"AC9/T23^2","v":{"v":1.6483051998946204E-14,"d":"1.648E-14"}}]
[{"$nulls":17},"I",{"$f":"AT41","v":{"v":0.010862132584639951,"d":"0.010862"}},{"v":0.10000000003620024,"d":"0.100000"},{"$nulls":21},"10. Click on the upper Data tab and click on Solver in the Analysis group (at the right)"]
[{"$nulls":17},"g H+",{"$f":"AU41","v":{"v":0.8987043944350366,"d":"0.899"}},{"v":0.7815939439265172,"d":"0.782"}]
[{"$nulls":17},"[H+]",{"$f":"D41","v":{"v":1.3096149588078488E-3,"d":"1.3096E-03"}},{"v":1.651244633436266e-13,"d":"1.6512E-13"},{"$nulls":21},"To learn from the authors' of Excel Solver about the design, uses and limitations"]
[{"$nulls":17},"[OH-]",{"$f":"AB21/D41","v":{"v":9.51968640834426e-12,"d":"9.5197E-12"}},{"v":0.099821986792137,"d":"9.9822E-02"},{"$nulls":21},"of the generalized reduced gradient method of nonlinear optimization, visit"]
[{"$nulls":17},"pH",{"$f":"B41","v":{"v":2.9292395076433086,"d":"2.929"}},{"v":12.889207394858074,"d":"12.889"},{"$nulls":21},"http://www.utexas.edu/courses/lasdon/design3.htm"]
[]
[]
[{"$nulls":17},"Color  coding"]
[{"$nulls":17},"D  o     n  o  t     c  h  a  n  g  e "]
[{"$nulls":17}," C h a n g e   c r i t e r i o u s l y"]
[{"$nulls":17},"Fill out, change or leave blank"]
[]
[]
[{"$nulls":18}," "]
[]
[]
["Ready for 100 real or simulated data points; to expand range to 160, copy all columns, from line 141 down to 200",{"$nulls":7},"To modify the axis of a plot od copy a figure, see instructions in cells  P443, 44 and 45 of Evaluation"]
["Vol. added","simulated or","calculated pH","[H]","dpH/dV","pHReg-pH","weighted","CHReg-CHcalc","CHReg","CHcalc","Dill. Titrant","Dil Titrand","den1","den2","den3","den4","den5","den6","den7","den1 titrant","den2 titrant","den3 titrant","h1","h2","h3","h4","h5","h6","h7","h1 titrant","h2 titrant","h3 titrant","I1","I2","I3","I4","I5","I6","I7","I1 titrant","I2 titrant","I3 titrant","Ipartial","Itotal","Click C22","I total","g H+",null,"pHReg- pH"]
["(mL)","measured pH","from regression","mol/L","for data weighting","for data weighting","residuals","mol/L","mol/L","mol/L",null,null,{"$f":"K3","v":"Citric acid"},"Glycine","Ascorbic acid ","Acetic acid","Ammonia","Carbonic acid","HCl","Strong ACID","Strong BASE","Carbonic ac.",{"$f":"K3","v":"Citric acid"},"Glycine","Ascorbic acid ","Acetic acid","Ammonia","Carbonic acid","HCl","Strong ACID","Strong BASE","Carbonic ac.",{"$f":"K3","v":"Citric acid"},"Glycine","Ascorbic acid ","Acetic acid","Ammonia","Carbonic acid","HCl",{"$f":"R3","v":"Strong ACID"},{"$f":"S3","v":"Strong BASE"},{"$f":"T3","v":"Carbonic ac."},"mol/L","mol/L","to update AT -->","applied\nmol/L","applied"]
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[null,null,"Titration curves and first derivatives overlay "]
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[{"$nulls":31},38.249999996660335,0.020564567119494646]
[{"$nulls":31},38.41666666331245,0.02335621625252605]
[{"$nulls":31},38.58333332996456,0.026296417933168805]
[{"$nulls":31},38.74999999661668,0.02907987817136893]
[{"$nulls":31},38.91666666326879,0.031705290647934474]
[{"$nulls":31},39.083333329920904,0.03417265536283752]
[{"$nulls":31},39.249999996573024,0.036481972316116634]
[{"$nulls":31},39.416666663225136,0.03863324150771824]
[{"$nulls":31},39.58333332987725,0.040626462937679256]
[{"$nulls":31},39.74999999652937,0.042461636606005396]
[{"$nulls":31},39.91666666318148,0.044138762512664444]
[{"$nulls":31},40.08333332983359,0.04565784065768337]
[{"$nulls":31},40.24999999648571,0.04701887104105653]
[{"$nulls":31},40.416666663137825,0.04822185366277308]
[{"$nulls":31},40.58333332978994,0.0492667885228392]
[{"$nulls":31},40.74999999644206,0.05015367562127003]
[{"$nulls":31},40.91666666309417,0.05088251495803349]
[{"$nulls":31},41.08333332974628,0.0514533065331574]
[{"$nulls":31},41.2499999963984,0.051866050346635245]
[{"$nulls":31},41.41666666305051,0.052120746398466984]
[{"$nulls":31},41.583333329702626,0.052217394688637966]
[{"$nulls":31},41.749999996354745,0.05215599521716283]
[{"$nulls":31},41.91666666300686,0.051936547984052256]
[{"$nulls":31},42.08333332965897,0.05155905298927025]
[{"$nulls":31},42.24999999631109,0.051023510232852794]
[{"$nulls":31},42.4166666629632,0.050329919714789305]
[{"$nulls":31},42.583333329615314,0.04947828143507556]
[{"$nulls":31},42.749999996267434,0.04846859539370512]
[{"$nulls":31},42.916666662919546,0.04731319293623454]
[{"$nulls":31},43.08333332957166,0.0461249550506393]
[{"$nulls":31},43.24999999622378,0.04496444418063997]
[{"$nulls":31},43.41666666287589,0.04383223845381988]
[{"$nulls":31},43.583333329528,0.04272833787016332]
[{"$nulls":31},43.74999999618012,0.041652742429696674]
[{"$nulls":31},43.916666662832235,0.040605452132377436]
[{"$nulls":31},44.08333332948435,0.03958646697823211]
[{"$nulls":31},44.24999999613647,0.03859578696726616]
[{"$nulls":31},44.41666666278858,0.03763341209946908]
[{"$nulls":31},44.58333332944069,0.03669934237483499]
[{"$nulls":31},44.74999999609281,0.035793577793391075]
[{"$nulls":31},44.91666666274492,0.034916118355094804]
[{"$nulls":31},45.083333329397036,0.03406696405997197]
[{"$nulls":31},45.249999996049155,0.033246114908028764]
[{"$nulls":31},45.41666666270127,0.03245357089925462]
[{"$nulls":31},45.58333332935338,0.03168933203365371]
[{"$nulls":31},45.7499999960055,0.030953398311211213]
[{"$nulls":31},45.91666666265761,0.030245769731959193]
[{"$nulls":31},46.083333329309724,0.029566446295858893]
[{"$nulls":31},46.24999999596184,0.02891542800292776]
[{"$nulls":31},46.416666662613956,0.02829271485318719]
[{"$nulls":31},46.58333332926607,0.027698306846598172]
[{"$nulls":31},46.74999999591819,0.027132203983189062]
[{"$nulls":31},46.9166666625703,0.026594406262949274]
[{"$nulls":31},47.08333332922241,0.02608491368588221]
[{"$nulls":31},47.24999999587453,0.02560372625198447]
[{"$nulls":31},47.416666662526644,0.02515084396124545]
[{"$nulls":31},47.58333332917876,0.02472626681368969]
[{"$nulls":31},47.749999995830876,0.024329994809303312]
[{"$nulls":31},47.91666666248299,0.02396202794808637]
[{"$nulls":31},48.0833333291351,0.023622366230041925]
[{"$nulls":31},48.24999999578722,0.023311009655166914]
[{"$nulls":31},48.41666666243933,0.02302795822346138]
[{"$nulls":31},48.583333329091445,0.022773211934917603]
[{"$nulls":31},48.749999995743565,0.022546770789564616]
[{"$nulls":31},48.91666666239568,0.02234863478735982]
[{"$nulls":31},49.08333332904779,0.022178803928348697]
[{"$nulls":31},49.24999999569991,0.022037278212485762]
[{"$nulls":31},49.41666666235202,0.021924057639803003]
[{"$nulls":31},49.583333329004134,0.02183914221029257]
[{"$nulls":31},49.74999999565625,0.02178253192396232]
[{"$nulls":31},49.916666662308366,0.02175422678078028]

{"sheet":"Database","index":9,"n_rows":301,"n_cols":26,"rows_kept":301,"hidden":true}
[null,"           ","                Database of dissociation constants of acids / protonation constants of bases"]
[null,"Most constants in this compilation of ~250 systems – but not all – were obtained at 25o C and are thermodynamic ones (I=0), as required by the pH_calc, Simulation and Regression modules."]
[null,"No guarantee is given that the compiled pKas or the calculations made with CurTiPot are correct or accurate. CurTiPot takes in account only protonation equilibria but other chemical reactions will occur for many combinations of two or more of the listed systems. "]
[null,"More systems, e.g., from the sources given next,  can be added: a) at the end of the list; b) in alphabetic order by inserting line(s) and updating the sequential numbering (column B)."]
[null,"Larger compilations of equilibrium constants and examples of on-line literature on acid-base equilibrium"]
[null,"SC-Database - Stability (equilibrium) constants database (from 1887 on, including IUPAC database)",{"$nulls":6},"http://www.acadsoft.co.uk/scdbase/scdbase.htm",{"$nulls":3},"Tutorial on acids and bases (and other) equilibria",{"$nulls":5},"http://www.asdlib.org/onlineArticles/ecourseware/Text_Files_files/Chapter6.pdf"]
[null,"Dissociation constants of  inorganic and organic compounds (compilation with 33 pages)",{"$nulls":6},"http://research.chem.psu.edu/brpgroup/pKa_compilation.pdf",{"$nulls":3},"Tutorial on titrations of acids and bases",{"$nulls":5},"http://www.asdlib.org/onlineArticles/ecourseware/Text_Files_files/Chapter9.pdf"]
[null,"Dissociation constants of organic compounds (~600 compounds)",{"$nulls":6},"http://www.zirchrom.com/organic.htm",{"$nulls":3},"Measurement of pH. Definitions, Standards and Procedures (IUPAC - 2002) ",{"$nulls":5},"http://www.iupac.org/publications/pac/2002/pdf/7411x2169.pdf"]
[null,"Computer calculated pKa values of any compound (by chemical name, CAS #, etc.) ",{"$nulls":6},"http://www.chemicalize.org/",{"$nulls":3},"Temperature dependence of potassium hydrogen phtalate 0.05 mol/kg buffer",{"$nulls":5},"http://nvl.nist.gov/pub/nistpubs/jres/081/1/V81.N01.A03.pdf"]
[null,"Martell, A. E., Smith, R. M., Critical Stability Constants, Vol. 1–4. Plenum Press: New York, 1976.",{"$nulls":10},"Primary standard buffer solutions pH at various temperatures",{"$nulls":5},"http://nvl.nist.gov/pub/nistpubs/jres/066/2/V66.N02.A06.pdf"]
[null,"Perrin, D. D., Dissociation Constants of Organic Bases in Aqueous Solution, Butterworths, London, 1965; Supplement, 1972.",{"$nulls":10},"Water,  hydrogen ion, hydroxide ion structures, properties, Kw, pH ",{"$nulls":5},"http://www1.lsbu.ac.uk/water/hydrogen_ions.html"]
[null,"Serjeant, E. P., and Dempsey, B., Ionization Constants of Organic Acids in Aqueous Solution, Pergamon, Oxford, 1979."]
[null,"Albert, A., \"Ionization Constants of Heterocyclic Substances\", in Physical Methods in Heterocyclic Chemistry, Katritzky, A. R., Ed., Academic Press, New York, 1963. ",{"$nulls":10},"Conversion of dissociation constants of acids into protonation constants of their conjugated bases"]
[null,"Perrin, D. D., Dempsey, B., and Serjeant, E. P., pKa Prediction for Organic Acids and Bases, Chapman & Hall, London, 1981.",{"$nulls":10},"pKa1 = logKpn","pKa4 = logKpn-3"]
[null,"Dawson, R. M. C., Elliot, D. C., Elliot, W. H., and Jones, K. M., Data for Biochemical Research, Oxford Science Publications, Oxford, 1986.",{"$nulls":10},"pKa2 = logKpn-1","pKa5 = logKpn-4",null," Overall protonation constants = bp = SKp"]
[null,"Acid base indicators - pKas, color transitions, etc.",{"$nulls":10},"pKa3 = logKpn-2","pKa6 = logKpn-5"]
[null,"Estimation of activity coefficients, gi, within CurTiPot - Davies equation:",{"$nulls":7},"Ionic strength ="]
[]
[null,null,"Acid or Base","Charge, fully",{"$nulls":6},"Temperat.","Ionic",null,"Molar mass"]
[{"$nulls":3},"deprotonated","pKa1","pKa2","pKa3","pKa4","pKa5","pKa6","ºC","strength","  Formula","g/mol"]
[null,null,"F R E Q U E N T L Y    U S E D "]
[null,1,"Acetic acid",-1,4.757,{"$nulls":5},25,0,"CH3COOH",60.052]
[null,2,"Ammonia",0,9.244,{"$nulls":5},25,0,"NH3",17.026]
[null,3,"Carbonic acid",-2,6.352,10.329,{"$nulls":4},25,0,"H2CO3"]
[null,4,"Citric acid",-3,3.128,4.761,6.396,{"$nulls":3},25,0,"H3C6H5O7 ",192.027]
[null,5,"EDTA",-4,-0.21,1.5,2.21,3.11,6.75,11.03,25,0,"C10H16N2O8",292.09]
[null,6,"HCl",-1,-7,{"$nulls":5},25,0,"HCl"]
[null,7,"Hydroxide ion",-1,15.745,{"$nulls":5},25,0,"NaOH"]
[null,8,"Phosphoric acid",-3,2.148,7.199,12.35,{"$nulls":3},25,0,"H3PO4",97.976]
[null,9,null,0,0]
[null,10,null,0,0]
[null,11,"A L P H A B E T I C   O R D E R ",null,"   Insert new lines anywere to add more systems; renumber column B",{"$nulls":5},"Find more values in the references and links"]
[null,12,"Acetamide ",0,0.63,{"$nulls":5},25,0,"C2H5NO ",59.067]
[null,13,"Acetic acid",-1,4.757,{"$nulls":5},25,0,"CH3COOH",60.052]
[null,14,"Acetoacetic acid ",-1,3.58,{"$nulls":5},18,0,"C4H6O3 ",102.089]
[null,15,"Acrylic acid ",-1,4.25,{"$nulls":5},25,0,"C3H4O2 ",72.063]
[null,16,"Adipic acid ",-2,4.43,5.41,{"$nulls":4},25,0,"C6H10O4 ",146.143]
[null,17,"Alanine ",-1,2.348,9.867,{"$nulls":4},25,0,"C3H7NO2",89.094]
[null,18,"Aminobenzene = aniline",0,4.6,{"$nulls":5},25,0,"C6H7N",93.13]
[null,19,"2-Aminobenzoic acid ",-1,2.108,4.946,{"$nulls":4},25,0,"C7H7NO2 ",137.138]
[null,20,"4-Animobenzoic acid ",-1,2.501,4.874,{"$nulls":4},25,0,"C7H7NO2 ",137.138]
[null,21,"2-Aminobutanoic acid ",-1,2.29,9.83,{"$nulls":4},25,0,"C4H9NO2 "]
[null,22,"6-Aminohexanoic acid ",-1,4.373,10.804,{"$nulls":4},25,0,"C6H13NO2 "]
[null,23,"5-Aminopentanoic acid ",-1,4.27,10.766,{"$nulls":4},25,0,"C5H11NO2 "]
[null,24,"2-Aminophenol",-1,4.78,9.97,{"$nulls":4},20,0,"C6H7NO"]
[null,25,"b-Alanine ",-1,3.55,10.24,{"$nulls":4},25,0,"C3H7NO2 "]
[null,26,"Ammonia",0,9.244,{"$nulls":5},25,0,"NH3",17.026]
[null,27,"Aniline ",0,4.63,{"$nulls":5},25,0,"C6H7N "]
[null,28,"Arginine",-1,1.823,8.991,12.48,{"$nulls":3},25,0,"C6H14N4O2 "]
[null,29,"Arsenic acid ",-3,2.24,6.96,11.5,{"$nulls":3},25,0,"H3AsO4 "]
[null,30,"Arsenous acid",-1,9.22,{"$nulls":6},0,"H3AsO3 "]
[null,31,"Ascorbic acid ",-2,4.1,11.79,{"$nulls":4},24,0,"C6H8O6 "]
[null,32,"Asparagine",-1,2.14,8.93,{"$nulls":4},25,0,"C4H8N2O3 "]
[null,33,"Aspartic acid ",-2,1.99,3.9,10.002,{"$nulls":3},25,0,"C4H7NO4 "]
[null,34,"Barbital",0,7.43,{"$nulls":5},25,0,"C8H12N2O3 ",184.19]
[null,35,"Barbituric acid ",-1,4.01,{"$nulls":5},25,0,"C4H4N2O3 ",128.09]
[null,36,"Benzenesulfonic acid ",-1,0.7,{"$nulls":5},25,0,"C6H6O3S "]
[null,37,"Benzoic acid ",-1,4.19,{"$nulls":5},25,0,"C7H6O2 "]
[null,38,"Benzylamine ",0,9.33,{"$nulls":5},25,0,"C7H9N "]
[null,39,"2-Benzylpyridine ",0,5.13,{"$nulls":5},25,0,"C12H11N "]
[null,40,"Betaine ",-1,1.83,{"$nulls":5},0,0,"C5H11NO2 "]
[null,41,"Boric acid ",-3,9.236,12.74,13.8,{"$nulls":3},20,0,"H3BO3"]
[null,42,"Butanoic acid ",-1,4.83,{"$nulls":5},25,0,"C4H8O2 "]
[null,43,"3-Butenoic acid ",-1,4.34,{"$nulls":5},25,0,"C4H6O2 "]
[null,44,"Butylamine ",0,10.77,{"$nulls":5},20,0,"C4H11N "]
[null,45,"sec-Butylamine ",0,10.56,{"$nulls":5},25,0,"C4H11N "]
[null,46,"tert-Butylamine ",0,10.68,{"$nulls":5},25,0,"C4H11N "]
[null,47,"Cadaverine ",0,10.05,10.93,{"$nulls":4},25,0,"C5H14N2 "]
[null,48,"Carbonic acid",-2,6.352,10.329,{"$nulls":4},25,0,"H2CO3"]
[null,49,"Catechol",-2,9.4,12.8,{"$nulls":4},25,0,"C6H4(OH)2",110.1]
[null,50,"Chloroacetic acid",-1,2.865,{"$nulls":5},25,0,"ClCH2COOH"]
[null,51,"2-Chloroaniline ",0,2.65,{"$nulls":5},25,0,"C6H6CIN "]
[null,52,"3-Chloroaniline ",0,3.46,{"$nulls":5},25,0,"C6H6CIN "]
[null,53,"4-Chloroaniline ",0,4.15,{"$nulls":5},25,0,"C6H6CIN "]
[null,54,"2-Chlorobenzoic acid ",-1,2.92,{"$nulls":5},25,0,"C7H5CIO2 "]
[null,55,"3-Chlorobenzoic acid ",-1,3.82,{"$nulls":5},25,0,"C7H5CIO2 "]
[null,56,"4-Chlorobenzoic acid ",-1,3.98,{"$nulls":5},25,0,"C7H5CIO2 "]
[null,57,"3-Chlorophenol ",-1,8.85,{"$nulls":5},25,0,"C6H5CIO "]
[null,58,"4-Chlorophenol ",-1,9.18,{"$nulls":5},25,0,"C6H5CIO "]
[null,59,"2-Chlorophenol ",-1,8.49,{"$nulls":5},25,0,"C6H5CIO "]
[null,60,"Choline ",0,13.9,{"$nulls":5},25,0,"C5H14NO "]
[null,61,"Chromic acid",-2,-0.2,6.51,{"$nulls":4},20,0,"H2CrO4"]
[null,62,"Citric acid",-3,3.128,4.761,6.396,{"$nulls":3},25,0,"H3C6H5O7 "]
[null,63,"Codeine ",0,8.21,{"$nulls":5},25,0,"C18H21NO3 "]
[null,64,"Creatinine ",0,4.83,9.2,{"$nulls":4},25,0,"C4H7N3O "]
[null,65,"m-Cresol ",-1,10.01,{"$nulls":5},25,0,"C7H8O "]
[null,66,"O-Cresol ",-1,10.2,{"$nulls":5},25,0,"C7H8O "]
[null,67,"p-Cresol ",-1,10.17,{"$nulls":5},25,0,"C7H8O "]
[null,68,"Cupferron",-1,4.37,{"$nulls":5},25,0,"C6H6N2O"]
[null,69,"Cyanic acid",-1,3.46,{"$nulls":7},"HCNO "]
[null,70,"Cysteine ",-2,1.71,8.36,10.77,{"$nulls":3},25,0,"C3H7NO2S "]
[null,71,"Decylamine ",0,10.64,{"$nulls":5},25,0,"C10H23N "]
[null,72,"2,4-Diaminobutanoic acid ",-1,1.85,8.24,10.44,{"$nulls":3},25,0,"C4H10N2O2 "]
[null,73,"Dichloroacetic acid",-1,1.3,{"$nulls":5},25,0,"Cl2CHCOOH"]
[null,74,"2,3-Dichlorophenol ",-1,7.46,{"$nulls":5},25,0,"C6H4Cl2O "]
[null,75,"Diethylamine",0,10.933,{"$nulls":5},25,0,"(CH3CH2)2NH"]
[null,76,"Diisopropylamine ",0,11.05,{"$nulls":5},25,0,"C6H15N "]
[null,77,"Dimethylamine",0,10.774,{"$nulls":5},25,0,"(CH3)2NH"]
[null,78,"Dimethylglyoxime",-2,10.66,12,{"$nulls":4},25,0,"C4H12O2N2"]
[null,79,"2,3-Dimethylpyridine ",0,6.58,{"$nulls":5},25,0,"C7H9N "]
[null,80,"2,4-Dimethylpyridine ",0,6.99,{"$nulls":5},25,0,"C7H9N "]
[null,81,"2,5-Dmethylpyridine ",0,6.4,{"$nulls":5},25,0,"C7H9N "]
[null,82,"2,6-Dimethylpyridine ",0,6.65,{"$nulls":5},25,0,"C7H9N "]
[null,83,"3,4-Dimethylpyridine ",0,6.46,{"$nulls":5},25,0,"C7H9N "]
[null,84,"3.5-Dimethylpyridine ",0,6.15,{"$nulls":5},25,0,"C7H9N "]
[null,85,"Dinicotinic acid ",-1,2.8,{"$nulls":5},25,0,"C7H5NO4 "]
[null,86,"Diphenylamine ",0,0.79,{"$nulls":5},25,0,"C12H11N "]
[null,87,"Dipicolinic acid ",-2,2.16,4.76,{"$nulls":4},25,0,"C7H5NO4 "]
[null,88,"Dopamine ",-1,8.9,10.6,{"$nulls":4},25,0,"C8H11NO2 ",153.18]
[null,89,"d-Ephedrine ",0,10.139,{"$nulls":5},10,0,"C10H15NO ",165.23]
[null,90,"Ethanolamine ",0,9.5,{"$nulls":5},25,0,"C2H7NO "]
[null,91,"Ethylamine",0,10.636,{"$nulls":5},25,0,"CH3CH2NH2"]
[null,92,"Ethylenediamine",0,6.848,9.928,{"$nulls":4},25,0,"H2NCH2CH2NH2"]
[null,93,"Ethylenediaminetetraacetic acid (EDTA)",-4,-0.21,1.5,2.21,3.11,6.75,11.03,25,0,"C10H16N2O8"]
[null,94,"Ethyleneimine ",0,8.01,{"$nulls":5},25,0,"C2H5N "]
[null,95,"2-Ethylpyridine ",0,5.89,{"$nulls":5},25,0,"C7H9N "]
[null,96,"Formic acid ",-1,3.745,{"$nulls":5},20,0,"HCOOH"]
[null,97,"Fumaric acid",-2,3.053,4.494,{"$nulls":4},25,0,"C4H4O4 ",116.07]
[null,98,"L-Glutamic acid ",-2,2.23,4.42,9.95,{"$nulls":3},25,0,"C5H9NO4 ",147.13]
[null,99,"L-Glutamine ",-1,2.17,9.13,{"$nulls":4},25,0,"C5H10N2O3 ",146.15]
[null,100,"L-Glutathione ",-2,2.12,3.59,8.75,9.65,null,null,25,0,"C10H17N3O6S "]
[null,101,"Glyceric acid ",-1,3.52,{"$nulls":5},25,0,"C3H6O4 "]
[null,102,"Glycerol ",-1,14.15,{"$nulls":5},25,0,"C3H8O3 "]
[null,103,"Glycine",-1,2.35,9.778,{"$nulls":4},25,0,"H2NCH2COOH",75.07]
[null,104,"Glycolic acid",-1,3.831,{"$nulls":5},25,0,"HOCH2COOH"]
[null,105,"Glyoxylic acid",-1,3.18,{"$nulls":5},25,0,"C2H2O3 "]
[null,106,"Heptanedioic acid ",-1,4.71,{"$nulls":5},25,0,"C7H12O4 "]
[null,107,"Heptanoic acid ",-1,4.89,{"$nulls":5},25,0,"C7H14O2 "]
[null,108,"Heptylamine ",0,10.67,{"$nulls":5},25,0,"C7H17N "]
[null,109,"Hexamethylenediamine ",0,11.857,10.762,{"$nulls":4},0,0,"C6H16N2 "]
[null,110,"Hexanoic acid ",-1,4.85,{"$nulls":5},25,0,"C6H12O2 "]
[null,111,"Hexylamine ",0,10.56,{"$nulls":5},25,0,"C6H15N "]
[null,112,"Histamine ",0,6.04,9.75,{"$nulls":4},25,0,"C5H9N3 "]
[null,113,"Histidine",-1,1.49,6.02,9.29,{"$nulls":3},25,0,"C6H9N3O2 "]
[null,114,"Hydrazine",0,8.07,{"$nulls":5},30,null,"N2H4"]
[null,115,"Hydroazoic ",-1,4.72,{"$nulls":7},"HN3 "]
[null,116,"Hydrogen bromide",-1,-9,{"$nulls":5},25,0,"HI"]
[null,117,"Hydrogen chloride",-1,-7,{"$nulls":5},25,0,"HCl"]
[null,118,"Hydrogen chromate ion ",-1,6.52,{"$nulls":7},"HCrO4- "]
[null,119,"Hydrogen cyanide",-1,9.21,{"$nulls":5},25,0,"HCN"]
[null,120,"Hydrogen fluoride",-1,3.17,{"$nulls":5},25,0,"HF"]
[null,121,"Hydrogen peroxide",-1,11.65,{"$nulls":5},25,0,"H2O2"]
[null,122,"Hydrogen selenate ion ",-1,1.66,{"$nulls":7},"HSeO4- "]
[null,123,"Hydrogen sulfide",-2,7.02,13.9,{"$nulls":4},25,0,"H2S"]
[null,124,"Hydrogen thiocyanate ",-1,0.9,{"$nulls":5},25,0,"HSCN"]
[null,125,"Hydroquinone ",0,10.35,{"$nulls":5},20,null,"C6H6O2 "]
[null,126,"Hydroxylamine",0,5.96,{"$nulls":5},25,0,"NH2OH"]
[null,127,"m-Hydroxybenzoic acid ",-2,4.06,9.92,{"$nulls":4},19,0,"C7H6O3 "]
[null,128,"p-Hydroxybenzoic acid ",-2,4.48,9.32,{"$nulls":4},19,0,"C7H6O3 "]
[null,129,"3-Hydroxypropanoic acid ",-1,4.51,{"$nulls":5},25,0,"C3H6O3 "]
[null,130,"8-Hydroxyquinoline",-1,4.91,9.81,{"$nulls":4},25,0]
[null,131,"Hypobromous",-1,8.63,{"$nulls":5},25,0,"HOBr"]
[null,132,"Hypochlorous",-1,7.53,{"$nulls":5},25,0,"HOCl"]
[null,133,"Hypoiodous",-1,10.64,{"$nulls":5},25,0,"HOI"]
[null,134,"Imidazole ",0,6.953,{"$nulls":5},25,0,"C3H4N2 ",68.08]
[null,135,"Iodic acid",-1,0.77,{"$nulls":5},25,0,"HIO3"]
[null,136,"Isocitric acid ",-3,3.29,4.71,6.4,{"$nulls":3},25,0,"C6H8O7 "]
[null,137,"Isoleucine",-1,2.319,9.754,{"$nulls":4},25,0,"C6H13NO2 ",131.18]
[null,138,"Lactic acid",-1,3.86,{"$nulls":7},"HC3H5O3 "]
[null,139,"l-Ephedrine ",0,9.958,{"$nulls":5},10,0,"C10H15NO ",165.23]
[null,140,"l-Leucine ",-1,2.328,9.744,{"$nulls":4},25,0,"C6H13NO2 "]
[null,141,"Lysine ",-1,1.83,9.08,10.9,{"$nulls":3},25,0,"C6H14N2O2 "]
[null,142,"Maleic acid ",-2,1.91,6.332,{"$nulls":4},25,0,"C4H4O4 "]
[null,143,"Malic acid ",-2,3.459,5.097,{"$nulls":4},25,0,"C4H6O5 "]
[null,144,"Malonic acid",-2,2.847,5.696,{"$nulls":4},25,0,"HOOCCH2COOH"]
[null,145,"Melamine = 1,3,5-triazine-2,4,6-triamine",0,5,{"$nulls":5},25,0,"C3H6N6 "]
[null,146,"Methionine = (S)-2-amino-4-(methylsulfanyl)-butanoic acid",-1,2.13,9.27,{"$nulls":4},25,0,"C5H11NO2S "]
[null,147,"Methylamine ",0,10.63,{"$nulls":5},25,0,"CH5N ",31.1]
[null,148,"2-Methylaniline = o-touidine = 2-amino-1-methylbenzene",0,4.447,{"$nulls":5},25,0,"C7H9N","107.17"]
[null,149,"4-Methylaniline = p-toluidine = 4-amino-1-methylbenzene",0,5.084,{"$nulls":5},25,0,"C7H9N","107.17"]
[null,150,"2-Methylbenzimidazole ",0,6.19,{"$nulls":5},25,0,"C8H8N2 "]
[null,151,"2-Methylbutanoic acid ",-1,4.8,{"$nulls":5},25,0,"C5H10O2 "]
[null,152,"3-Methylbutanoic acid ",-1,4.77,{"$nulls":5},25,0,"C5H10O2 "]
[null,153,"Methylmalonic acid ",-2,3.07,5.76,{"$nulls":4},25,0,"C4H6O4 "]
[null,154,"Methyl-1-naphthylamine ",0,3.67,{"$nulls":5},27,0,"C11H11N "]
[null,155,"4-Methylpentanoic acid ",-1,4.84,{"$nulls":5},18,0,"C6H12O2 "]
[null,156,"1-Methylpiperidine ",0,10.08,{"$nulls":5},25,0,"C6H13N "]
[null,157,"2-Methylphenol = o-cresol",-1,10.28,{"$nulls":5},25,0,"C7H8O ","108.14"]
[null,158,"4-Methylphenol = p-cresol",-1,10.26,{"$nulls":5},25,0,"C7H8O ","108.14"]
[null,159,"2-Methylpyridine ",0,5.97,{"$nulls":5},20,0,"C6H7N "]
[null,160,"3-Methylpyridine ",0,5.68,{"$nulls":5},20,0,"C6H7N "]
[null,161,"4-Methylpyridine ",0,6.02,{"$nulls":5},20,0,"C6H7N "]
[null,162,"Morphine ",0,8.21,{"$nulls":5},25,0,"C17H19NO3 "]
[null,163,"Morpholine ",0,8.33,{"$nulls":5},25,0,"C4H9NO "]
[null,164,"1-Naphthol ",-1,9.34,{"$nulls":5},25,0,"C10H8O "]
[null,165,"2-Naphthol ",-1,9.51,{"$nulls":5},25,0,"C10H8O "]
[null,166,"Nicotine ",0,3.12,8.02,{"$nulls":4},25,0,"C10H14N2 "]
[null,167,"Nitrilotriacetic acid",-3,1.1,1.65,2.94,10.334,null,null,20,0]
[null,168,"2-Nitroaniline ",0,-0.26,{"$nulls":5},25,0,"C6H6N2O2 "]
[null,169,"3-Nitroaniline ",0,2.466,{"$nulls":5},25,0,"C6H6N2O2 "]
[null,170,"4-Nitroaniline ",0,1,{"$nulls":5},25,0,"C6H6N2O2 "]
[null,171,"2-Nitrobenzoic acid",-1,2.179,{"$nulls":5},25,0,"C7H5NO4 "]
[null,172,"2-Nitrophenol",-1,7.21,{"$nulls":5},25,0,"C6H5NO3 "]
[null,173,"3-Nitrophenol",-1,8.39,{"$nulls":5},25,0,"C6H5NO3 "]
[null,174,"4-Nitrophenol ",-1,7.15,{"$nulls":5},25,0,"C6H5NO3 "]
[null,175,"3-Nitrobenzoic acid",-1,3.449,{"$nulls":5},25,0,"C7H5NO4 "]
[null,176,"4-Nitrobenzoic acid ",-1,3.442,{"$nulls":5},25,0,"C7H5NO4 "]
[null,177,"Nitrous acid",-1,3.15,{"$nulls":5},25,0,"HNO2"]
[null,178,"Noradrenaline ",-1,8.64,9.7,{"$nulls":4},25,0,"C8H11NO3 "]
[null,179,"Octadecylamine ",0,10.6,{"$nulls":5},25,0,"C18H39N "]
[null,180,"Octanedioic acid ",-1,4.52,{"$nulls":5},25,0,"C8H14O4 "]
[null,181,"Octanoic acid ",-1,4.89,{"$nulls":5},25,0,"C8H16O2 "]
[null,182,"Oxalic acid",-2,1.252,4.266,{"$nulls":4},25,0,"C2H2O4 "]
[null,183,"Oxaloacetic acid ",-2,2.22,3.89,13.03,{"$nulls":3},25,0,"C4H4O5 "]
[null,184,"Papaverine ",0,6.4,{"$nulls":5},25,0,"C20H21NO4 "]
[null,185,"Pentanoic acid ",-1,4.84,{"$nulls":5},25,0,"C5H10O2 "]
[null,186,"Perchloric acid",-1,-10,{"$nulls":5},25,0,"HClO4"]
[null,187,"p-Periodic acid",-2,1.55,8.28,{"$nulls":6},"H5IO6 "]
[null,188,"1,10-Phenanthroline ",0,4.84,{"$nulls":5},25,0,"C12H8N2 ",180.3]
[null,189,"m-Phenetidine ",0,4.18,{"$nulls":5},25,0,"C8H11NO "]
[null,190,"o-Phenetidine ",0,4.43,{"$nulls":5},28,0,"C8H11NO "]
[null,191,"Phenol",-1,9.98,{"$nulls":5},25,0,"HC6H5O "]
[null,192,"Phenylacetic acid ",-1,4.28,{"$nulls":5},18,0,"C8H8O2 "]
[null,193,"Phenylalanine ",-1,2.2,9.31,{"$nulls":4},25,0,"C9H11NO2 "]
[null,194,"Phenylethylamine ",0,9.84,{"$nulls":5},25,0,"C8H11N "]
[null,195,"Phenylglycine ",-1,1.83,4.39,{"$nulls":4},25,0,"C8H9NO2 "]
[null,196,"Phosphoric acid",-3,2.148,7.199,12.35,{"$nulls":3},25,0,"H3PO4"]
[null,197,"m-Phthalic acid ",-2,3.54,4.6,{"$nulls":4},25,0,"C8H6O4 ",166.14]
[null,198,"o-Phthalic acid",-2,2.95,5.408,{"$nulls":4},25,0,"C8H6O4 ",166.14]
[null,199,"p-Phthalic acid ",-2,3.51,4.82,{"$nulls":4},25,0,"C8H6O4 "]
[null,200,"Picolinic acid ",-2,1.07,5.25,{"$nulls":4},25,0,"C6H5NO2 "]
[null,201,"Picric acid ",-1,0.38,{"$nulls":7},"C6H3N3O7 "]
[null,202,"Pilocarpine ",0,6.87,{"$nulls":5},30,0,"C11H16N2O2 ",208.259]
[null,203,"Piperazine ",0,5.56,9.83,{"$nulls":4},23,0,"C4H10N2 "]
[null,204,"Piperidine",0,7.53,11.123,{"$nulls":4},25,0,"C5H11N",85.15]
[null,205,"p-Phenetidine ",0,5.2,{"$nulls":5},28,0,"C8H11NO "]
[null,206,"Proline",-1,1.952,10.64,{"$nulls":4},25,0,"C5H9NO2",115.13]
[null,207,"Propanoic acid",-1,4.874,{"$nulls":5},25,0,"CH3CH2COOH"]
[null,208,"Propylamine",0,10.566,{"$nulls":5},25,0,"CH3CH2CH2NH2"]
[null,209,"Purine ",0,2.3,8.96,{"$nulls":4},20,0,"C5H4N4 ",120.11]
[null,210,"Pyridine",0,5.229,{"$nulls":5},25,0,"C5H5N",79.1]
[null,211,"3-Pyridinecarboxylic acid ",-1,4.85,{"$nulls":5},25,0,"C6H5NO2 "]
[null,212,"4-Pyridinecarboxylic acid ",-1,4.96,{"$nulls":5},25,0,"C6H5NO2 "]
[null,213,"Pyrimidine ",0,6.35,{"$nulls":5},20,0,"C11H8N2 "]
[null,214,"Pyrocatechol ",-2,9.4,12.8,{"$nulls":4},20,0,"C6H6O2 ",110.1]
[null,215,"Pyrophosphoric ",-4,1.52,2.36,6.6,9.25,{"$nulls":4},"H4P2O7 ",177.98]
[null,216,"Pyrrolidine ",0,11.27,{"$nulls":5},25,0,"C4H9N "]
[null,217,"Pyruvic acid ",-1,2.39,{"$nulls":5},25,0,"C3H4O3 ",88.06]
[null,218,"Quinine ",0,4.13,8.52,{"$nulls":4},25,0,"C20H24N2O2 ",324.42]
[null,219,"Quinoline ",0,4.9,{"$nulls":5},20,0,"C9H7N ",129.16]
[null,220,"Resorcinol",-2,9.3,11.06,{"$nulls":4},25,0,"C6H6O2 ",110.1]
[null,221,"Saccharin ",-1,11.68,{"$nulls":5},18,0,"C7H5NO3S "]
[null,222,"Salicylic acid",-2,2.97,13.74,{"$nulls":4},25,0,"C7H6O3 ",138.12]
[null,223,"Selenic acid",-1,1.92,{"$nulls":5},25,0,"H2SeO4"]
[null,224,"Selenous acid",-2,2.64,8.28,{"$nulls":5},0,"H2SeO3 "]
[null,225,"Serine ",-1,2.19,9.05,{"$nulls":4},25,0,"C3H7NO3",105.09]
[null,226,"o-Silicic acid",-2,9.66,11.7,{"$nulls":6},"H4SiO4"]
[null,227,"m-Silicic acid",-2,9.7,12,{"$nulls":6},"H2SiO3"]
[null,228,"Strychnine ",0,8.26,{"$nulls":5},25,0,"C21H22N2O2 ",334.41]
[null,229,"Succinic acid",-2,4.207,5.636,{"$nulls":6},"HOOCCH2CH2COOH",118.09]
[null,230,"Sulfuric acid",-2,-3,1.99,{"$nulls":4},25,0,"H2SO4 ",98.08]
[null,231,"Sulfurous acid",-2,1.91,7.18,{"$nulls":4},25,0,"H2SO3",82.07]
[null,232,"d-Tartaric acid",-2,3.036,4.366,{"$nulls":4},25,0,"C4H6O6 ",150.09]
[null,233,"meso-Tartaric acid ",-2,3.22,4.82,{"$nulls":4},25,0,"C4H6O6 ",150.09]
[null,234,"Terephthalic acid ",-1,3.51,{"$nulls":5},25,0,"C8H6O4 "]
[null,235,"Thiazole ",0,2.44,{"$nulls":5},20,0,"C3H3NS "]
[null,236,"Thioacetic acid ",-1,3.33,{"$nulls":5},25,0,"C2H4OS "]
[null,237,"Thiosulfuric acid",-2,0.6,1.63,{"$nulls":4},25,0,"H2S2O3"]
[null,238,"Threonine",-1,2.088,9.1,{"$nulls":4},25,0,"C4H9NO3",119.12]
[null,239,"m-Toluic acid ",-1,4.27,{"$nulls":5},25,0,"C8H8O2 "]
[null,240,"o-Toluic acid ",-1,3.91,{"$nulls":5},25,0,"C8H8O2 "]
[null,241,"p-Toluic acid ",-1,4.36,{"$nulls":5},25,0,"C8H8O2 "]
[null,242,"Trichloroacetic acid",-1,0.87,{"$nulls":5},25,0,"Cl3CCOOH"]
[null,243,"Triethanolamine",0,7.762,{"$nulls":5},25,0,"(HOCH2CH2)3NH"]
[null,244,"Triethylamine",0,10.715,{"$nulls":5},25,0,"(CH3CH2)3NH"]
[null,245,"Trimethylacetic acid   ",-1,5.03,{"$nulls":5},25,0,"C5H10O2 "]
[null,246,"Trimethylamine",0,9.8,{"$nulls":5},25,0,"(CH3)3NH"]
[null,247,"Tris(hydroxymethyl)- aminomethane (tris)",0,8.075,{"$nulls":5},25,0,"(HOCH2)3CNH3"]
[null,248,"Tryptophan",-1,2.35,9.54,{"$nulls":4},25,0,"C11H12N2O2 "]
[null,249,"Tyramine ",0,9.74,10.52,{"$nulls":4},25,0,"C8H11NO "]
[null,250,"Tyrosine ",-1,2.17,9.19,10.47,{"$nulls":3},25,0,"C9H11NO3 "]
[null,251,"Urea ",0,0.1,{"$nulls":5},21,0,"CH4N2O "]
[null,252,"Uric acid ",-1,3.89,{"$nulls":5},12,0,"C5H4N4O3 "]
[null,253,"Valine ",-1,2.286,9.718,{"$nulls":4},25,0,"C5H11NO2 "]
[null,254,"I N D I C A T O R S",{"$nulls":11},"pKa","pH < pKa","pH = pKa","pH>pka",{"$nulls":3},"Other color numbers"]
[null,255,"Thymol Blue (pKa 1.7)",-2,1.7,8.9,{"$nulls":6},"C27H30O5S",{"v":466.59,"d":"466.590"},1.7,5263615,4107000,4907000,null,null,"green",1701178,8374896,52377,7722000,1702000]
[null,256,"Methyl Orange (pKa 3.5)",-2,-1,3.47,{"$nulls":6},"C14H14N3NaO3S",{"v":327.33,"d":"327.330"},3.47,5263615,4961023,4907000,null,null,"blue",16763955,16750899,15456000]
[null,257,"Bromocresol Green (pKa 4.8)",-2,-1,4.8,{"$nulls":6},"C21H14Br4O5S",{"v":698.01,"d":"698.010"},4.8,4907000,52377,16750899,null,null,"red",7039480,5263615,14666000]
[null,258,"Methyl Red (pKa 5.1)",-1,5.1,{"$nulls":7},"C15H15N3O2",{"v":269.3,"d":"269.300"},5.1,5263615,4961023,4907000,null,null,"yellow",4907000,10285055,3339000,60395]
[null,259,"Bromothymol Blue (pKa 7.1)",-1,7.1,{"$nulls":7},"C27H28Br2O5S",{"v":624.38,"d":"624.380"},7.1,4907000,6813000,16750899,null,null,"white",16777215]
[null,260,"Phenol Red (pKa 7.7)",-2,1.2,7.7,{"$nulls":6},"C19H14O5S",{"v":354.38,"d":"354.380"},7.7,4907000,4961023,5263615,null,null,"orange",4961023]
[null,261,"Thymol Blue (pKa 8.9)",-2,1.7,8.9,{"$nulls":6},"C27H30O5S",{"v":466.59,"d":"466.590"},8.9,4907000,52377,16750899]
[null,262,"Phenolphthalein",-2,9.5,9.7,{"$nulls":6},"C20H14O4",{"v":318.32,"d":"318.320"},9.7,15395562,16564985,16419572]
[null,263,"Alizarine yellow R (pKa 11)",-1,11,{"$nulls":7},"C13H9N3O5 ",{"v":287.23,"d":"287.230"},11,4907000,4961023,5263615]
[null,264]
[null,265]
[null,266]
[null,267]
[null,268]
[null,269]
[null,270]
[null,271]
[null,272]
[null,273]
[null,274]
[null,275]
[null,276]
[null,277]
[null,278]
[null,279]
[null,280]